Reduction of Pu(IV) and Np(VI) with carbohydrazide in nitric acid solution
The reduction of Pu(IV) and Np(VI) with carbohydrazide (NH 2 NH) 2 CO in 1–6 M HNO 3 solutions was studied. The Pu(IV) reduction is described by a first-order rate equation with respect to Pu(IV). At [HNO 3 ] ≥ 3 M, the reaction becomes reversible. The rate constants of the forward and reverse react...
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Veröffentlicht in: | Radiochemistry (New York, N.Y.) N.Y.), 2012-04, Vol.54 (2), p.143-148 |
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Sprache: | eng |
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