Reduction of Pu(IV) and Np(VI) with carbohydrazide in nitric acid solution

The reduction of Pu(IV) and Np(VI) with carbohydrazide (NH 2 NH) 2 CO in 1–6 M HNO 3 solutions was studied. The Pu(IV) reduction is described by a first-order rate equation with respect to Pu(IV). At [HNO 3 ] ≥ 3 M, the reaction becomes reversible. The rate constants of the forward and reverse react...

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Veröffentlicht in:Radiochemistry (New York, N.Y.) N.Y.), 2012-04, Vol.54 (2), p.143-148
Hauptverfasser: Volk, V. I., Marchenko, V. I., Dvoeglazov, K. N., Alekseenko, V. N., Bychkov, S. I., Pavlyukevich, E. Yu, Bondin, V. V., D’yachenko, A. S.
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Sprache:eng
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