Superionic conductivity and switching effect with memory in TlInSe2 and TlInTe2 crystals

The temperature dependences of the conductivity σ( T ) and the switching and memory effects in one-dimensional TlInSe 2 and TlInTe 2 single crystals have been studied. A specific feature is found in the dependence σ( T ) above 333 K, which is related to the transition of crystals to the state with s...

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Veröffentlicht in:Semiconductors (Woodbury, N.Y.) N.Y.), 2011-11, Vol.45 (11), p.1387-1390
Hauptverfasser: Sardarly, R. M., Samedov, O. A., Abdullayev, A. P., Salmanov, F. T., Alekperov, O. Z., Huseynov, E. K., Aliyeva, N. A.
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container_end_page 1390
container_issue 11
container_start_page 1387
container_title Semiconductors (Woodbury, N.Y.)
container_volume 45
creator Sardarly, R. M.
Samedov, O. A.
Abdullayev, A. P.
Salmanov, F. T.
Alekperov, O. Z.
Huseynov, E. K.
Aliyeva, N. A.
description The temperature dependences of the conductivity σ( T ) and the switching and memory effects in one-dimensional TlInSe 2 and TlInTe 2 single crystals have been studied. A specific feature is found in the dependence σ( T ) above 333 K, which is related to the transition of crystals to the state with superionic conductivity. It is suggested that the ion conductivity is caused by the diffusion of Tl + ions over vacancies in the thallium sublattice between (In 3+ Te 2 2− ) − and (In 3+ Se 2 2− ) − nanochains (nanorods). S -type switching and memory effects are revealed in TlInSe 2 and TlInTe 2 crystals, as well as voltage oscillations in the range of negative differential resistance. It is suggested that the switching effect and voltage oscillations are related to the transition of crystals to the superionic state, which is accompanied by “melting” of the Tl sublattice. The effect of electric-field-induced transition of TlInSe 2 and TlInTe 2 crystals to the superionic state is found.
doi_str_mv 10.1134/S1063782611110224
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subjects Diffusion
Magnetic Materials
Magnetism
Nonelectronic Properties of Semiconductors (Atomic Structure
Physics
Physics and Astronomy
title Superionic conductivity and switching effect with memory in TlInSe2 and TlInTe2 crystals
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