Size effects in [N(CH3)4]2Zn0.58Cu0.42Cl4 crystals

The temperature dependences of birefringence in thin [N(CH 3 ) 4 ] 2 Zn 0.58 Cu 0.42 Cl 4 crystals in the thickness range 20 × 10 −6 ≤ d ≤ 500 ↾ 10 −6 m have been investigated. An increase in the temperatures of the parent phase-incommensurate phase and incommensurate phase-ferroelectric phase trans...

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Veröffentlicht in:Crystallography reports 2013, Vol.58 (1), p.122-128
Hauptverfasser: Sveleba, S. A., Karpa, I. V., Katerynchuk, I. N., Furgala, Yu. M., Semotyuk, O. V., Kunyo, I. M., Fitsych, E. I., Pankivskyi, Yu. I.
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container_end_page 128
container_issue 1
container_start_page 122
container_title Crystallography reports
container_volume 58
creator Sveleba, S. A.
Karpa, I. V.
Katerynchuk, I. N.
Furgala, Yu. M.
Semotyuk, O. V.
Kunyo, I. M.
Fitsych, E. I.
Pankivskyi, Yu. I.
description The temperature dependences of birefringence in thin [N(CH 3 ) 4 ] 2 Zn 0.58 Cu 0.42 Cl 4 crystals in the thickness range 20 × 10 −6 ≤ d ≤ 500 ↾ 10 −6 m have been investigated. An increase in the temperatures of the parent phase-incommensurate phase and incommensurate phase-ferroelectric phase transitions has been found. The reasons for the shift in the phase transition temperatures with a decrease in the thickness of [N(CH 3 ) 4 ] 2 Zn 0.58 Cu 0.42 Cl 4 crystal and the size effect in crystals with an incommensurate superstructure are discussed.
doi_str_mv 10.1134/S1063774513010124
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Lattice Dynamics and Phase Transitions
Physics
Physics and Astronomy
title Size effects in [N(CH3)4]2Zn0.58Cu0.42Cl4 crystals
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