Nuclear magnetic relaxation of protons in “polyantimonic acid–phosphate” composites
The results of studying MeH 2 PO 4 (Me = K, Na)/Sb 2 O 5 · 2.7H 2 O composites using the pulsed NMR spectroscopy technique at the temperatures of 20–140°C are presented. The contribution of interfaces, a subsystem formed due to interaction between the components of the composite, is identified in th...
Gespeichert in:
| Veröffentlicht in: | Russian journal of electrochemistry 2016-07, Vol.52 (7), p.685-689 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 689 |
|---|---|
| container_issue | 7 |
| container_start_page | 685 |
| container_title | Russian journal of electrochemistry |
| container_volume | 52 |
| creator | Neustroev, A. S. Zakhar’evich, D. A. Chernov, V. M. |
| description | The results of studying MeH
2
PO
4
(Me = K, Na)/Sb
2
O
5
· 2.7H
2
O composites using the pulsed NMR spectroscopy technique at the temperatures of 20–140°C are presented. The contribution of interfaces, a subsystem formed due to interaction between the components of the composite, is identified in the signals of transverse magnetization decay. Protons near the interfaces are in two states, mobile and bound, and the fraction of mobile protons increases with the temperature, as all protons prove to be in the mobile state at the temperatures above 80°C. The composition of the interface is determined by the ion exchange reaction between components and is close to phosphoric acid. The obtained results explain the observed increase in conductivity of composites as compared to pure components. |
| doi_str_mv | 10.1134/S1023193516070132 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref_sprin</sourceid><recordid>TN_cdi_crossref_primary_10_1134_S1023193516070132</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1134_S1023193516070132</sourcerecordid><originalsourceid>FETCH-LOGICAL-c358t-fa03e1b22bfad7455f78cd838bfe011795cd6648e66b743906d08845e32f0bc3</originalsourceid><addsrcrecordid>eNp9kM1KAzEUhYMoWKsP4C4vMJqbzE9mKcU_KLqwG1dDJpO0KTPJkKRgd30Ht_pyfRJT6k5wdQ-c8x0uB6FrIDcALL99A0IZ1KyAklQEGD1BkyR5xlhOT5NOdnbwz9FFCGtCCK-gnqD3l43slfB4EEuropHYq158iGicxU7j0bvobMDG4v3ua3T9VthoBmdTUkjT7Xef48qFcSWi2u--sXTD6IKJKlyiMy36oK5-7xQtHu4Xs6ds_vr4PLubZ5IVPGZaEKagpbTVoqvyotAVlx1nvNWKAFR1IbuyzLkqy7bKWU3KjnCeF4pRTVrJpgiOtdK7ELzSzejNIPy2AdIcpmn-TJMYemRCytql8s3abbxNX_4D_QD8D2oL</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Nuclear magnetic relaxation of protons in “polyantimonic acid–phosphate” composites</title><source>SpringerLink Journals - AutoHoldings</source><creator>Neustroev, A. S. ; Zakhar’evich, D. A. ; Chernov, V. M.</creator><creatorcontrib>Neustroev, A. S. ; Zakhar’evich, D. A. ; Chernov, V. M.</creatorcontrib><description>The results of studying MeH
2
PO
4
(Me = K, Na)/Sb
2
O
5
· 2.7H
2
O composites using the pulsed NMR spectroscopy technique at the temperatures of 20–140°C are presented. The contribution of interfaces, a subsystem formed due to interaction between the components of the composite, is identified in the signals of transverse magnetization decay. Protons near the interfaces are in two states, mobile and bound, and the fraction of mobile protons increases with the temperature, as all protons prove to be in the mobile state at the temperatures above 80°C. The composition of the interface is determined by the ion exchange reaction between components and is close to phosphoric acid. The obtained results explain the observed increase in conductivity of composites as compared to pure components.</description><identifier>ISSN: 1023-1935</identifier><identifier>EISSN: 1608-3342</identifier><identifier>DOI: 10.1134/S1023193516070132</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Electrochemistry ; Physical Chemistry</subject><ispartof>Russian journal of electrochemistry, 2016-07, Vol.52 (7), p.685-689</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-fa03e1b22bfad7455f78cd838bfe011795cd6648e66b743906d08845e32f0bc3</citedby><cites>FETCH-LOGICAL-c358t-fa03e1b22bfad7455f78cd838bfe011795cd6648e66b743906d08845e32f0bc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1023193516070132$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1023193516070132$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Neustroev, A. S.</creatorcontrib><creatorcontrib>Zakhar’evich, D. A.</creatorcontrib><creatorcontrib>Chernov, V. M.</creatorcontrib><title>Nuclear magnetic relaxation of protons in “polyantimonic acid–phosphate” composites</title><title>Russian journal of electrochemistry</title><addtitle>Russ J Electrochem</addtitle><description>The results of studying MeH
2
PO
4
(Me = K, Na)/Sb
2
O
5
· 2.7H
2
O composites using the pulsed NMR spectroscopy technique at the temperatures of 20–140°C are presented. The contribution of interfaces, a subsystem formed due to interaction between the components of the composite, is identified in the signals of transverse magnetization decay. Protons near the interfaces are in two states, mobile and bound, and the fraction of mobile protons increases with the temperature, as all protons prove to be in the mobile state at the temperatures above 80°C. The composition of the interface is determined by the ion exchange reaction between components and is close to phosphoric acid. The obtained results explain the observed increase in conductivity of composites as compared to pure components.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrochemistry</subject><subject>Physical Chemistry</subject><issn>1023-1935</issn><issn>1608-3342</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KAzEUhYMoWKsP4C4vMJqbzE9mKcU_KLqwG1dDJpO0KTPJkKRgd30Ht_pyfRJT6k5wdQ-c8x0uB6FrIDcALL99A0IZ1KyAklQEGD1BkyR5xlhOT5NOdnbwz9FFCGtCCK-gnqD3l43slfB4EEuropHYq158iGicxU7j0bvobMDG4v3ua3T9VthoBmdTUkjT7Xef48qFcSWi2u--sXTD6IKJKlyiMy36oK5-7xQtHu4Xs6ds_vr4PLubZ5IVPGZaEKagpbTVoqvyotAVlx1nvNWKAFR1IbuyzLkqy7bKWU3KjnCeF4pRTVrJpgiOtdK7ELzSzejNIPy2AdIcpmn-TJMYemRCytql8s3abbxNX_4D_QD8D2oL</recordid><startdate>20160701</startdate><enddate>20160701</enddate><creator>Neustroev, A. S.</creator><creator>Zakhar’evich, D. A.</creator><creator>Chernov, V. M.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160701</creationdate><title>Nuclear magnetic relaxation of protons in “polyantimonic acid–phosphate” composites</title><author>Neustroev, A. S. ; Zakhar’evich, D. A. ; Chernov, V. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-fa03e1b22bfad7455f78cd838bfe011795cd6648e66b743906d08845e32f0bc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electrochemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Neustroev, A. S.</creatorcontrib><creatorcontrib>Zakhar’evich, D. A.</creatorcontrib><creatorcontrib>Chernov, V. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Neustroev, A. S.</au><au>Zakhar’evich, D. A.</au><au>Chernov, V. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nuclear magnetic relaxation of protons in “polyantimonic acid–phosphate” composites</atitle><jtitle>Russian journal of electrochemistry</jtitle><stitle>Russ J Electrochem</stitle><date>2016-07-01</date><risdate>2016</risdate><volume>52</volume><issue>7</issue><spage>685</spage><epage>689</epage><pages>685-689</pages><issn>1023-1935</issn><eissn>1608-3342</eissn><abstract>The results of studying MeH
2
PO
4
(Me = K, Na)/Sb
2
O
5
· 2.7H
2
O composites using the pulsed NMR spectroscopy technique at the temperatures of 20–140°C are presented. The contribution of interfaces, a subsystem formed due to interaction between the components of the composite, is identified in the signals of transverse magnetization decay. Protons near the interfaces are in two states, mobile and bound, and the fraction of mobile protons increases with the temperature, as all protons prove to be in the mobile state at the temperatures above 80°C. The composition of the interface is determined by the ion exchange reaction between components and is close to phosphoric acid. The obtained results explain the observed increase in conductivity of composites as compared to pure components.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1023193516070132</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1023-1935 |
| ispartof | Russian journal of electrochemistry, 2016-07, Vol.52 (7), p.685-689 |
| issn | 1023-1935 1608-3342 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S1023193516070132 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Electrochemistry Physical Chemistry |
| title | Nuclear magnetic relaxation of protons in “polyantimonic acid–phosphate” composites |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-05T13%3A45%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_sprin&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Nuclear%20magnetic%20relaxation%20of%20protons%20in%20%E2%80%9Cpolyantimonic%20acid%E2%80%93phosphate%E2%80%9D%20composites&rft.jtitle=Russian%20journal%20of%20electrochemistry&rft.au=Neustroev,%20A.%20S.&rft.date=2016-07-01&rft.volume=52&rft.issue=7&rft.spage=685&rft.epage=689&rft.pages=685-689&rft.issn=1023-1935&rft.eissn=1608-3342&rft_id=info:doi/10.1134/S1023193516070132&rft_dat=%3Ccrossref_sprin%3E10_1134_S1023193516070132%3C/crossref_sprin%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |