Mass transport to and within porous electrodes. Linear sweep voltammetry and the effects of pore size: The prediction of double peaks for a single electrode process

We simulate an electrode modified with a conducting porous film, where the electrolysis occurs both at the surface of the film and within it, in order to study the effect of pore size on the peak current in linear sweep voltammetry. For redox systems with reversible electrode kinetics we find that f...

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Veröffentlicht in:Russian journal of electrochemistry 2012-06, Vol.48 (6), p.629-635
Hauptverfasser: Henstridge, M. C., Dickinson, E. J. F., Compton, R. G.
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Sprache:eng
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