Partial oxidation of methane to synthesis gas over NdCaCoO4 catalyst: Kinetic modeling of autothermal reforming
Partial oxidation of methane to synthesis gas using a highly selective catalyst based on NdCaCoO 4 has been studied, and rate constants have been determined. To determine the kinetic constants in a thin bed of the catalyst with a mass of 0.1 g, a model of isothermal syngas production process has bee...
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| Veröffentlicht in: | Petroleum chemistry 2015-07, Vol.55 (6), p.455-461 |
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| container_title | Petroleum chemistry |
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| creator | Gartman, T. N. Sovetin, F. S. Borovkova, E. A. Shvets, V. F. Kozlovskii, R. A. Loktev, A. S. Lebedev, Yu. V. Dedov, A. G. Moiseev, I. I. |
| description | Partial oxidation of methane to synthesis gas using a highly selective catalyst based on NdCaCoO
4
has been studied, and rate constants have been determined. To determine the kinetic constants in a thin bed of the catalyst with a mass of 0.1 g, a model of isothermal syngas production process has been implemented and objective functions and computational algorithm to minimize the mismatch criterion between calculated and experimental data have been selected. The oxidative methane reforming process has been modeled in the isothermal and autothermal modes. The calculation results for the isothermal mode have been found to agree with experimental data. |
| doi_str_mv | 10.1134/S0965544115060043 |
| format | Article |
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has been studied, and rate constants have been determined. To determine the kinetic constants in a thin bed of the catalyst with a mass of 0.1 g, a model of isothermal syngas production process has been implemented and objective functions and computational algorithm to minimize the mismatch criterion between calculated and experimental data have been selected. The oxidative methane reforming process has been modeled in the isothermal and autothermal modes. The calculation results for the isothermal mode have been found to agree with experimental data.</description><identifier>ISSN: 0965-5441</identifier><identifier>EISSN: 1555-6239</identifier><identifier>DOI: 10.1134/S0965544115060043</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Industrial Chemistry/Chemical Engineering</subject><ispartof>Petroleum chemistry, 2015-07, Vol.55 (6), p.455-461</ispartof><rights>Pleiades Publishing, Ltd. 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c325t-e5a6b9d0db314097300796ead4cf5c199563086ff7a04d2e52b9c0cbb81fcf933</citedby><cites>FETCH-LOGICAL-c325t-e5a6b9d0db314097300796ead4cf5c199563086ff7a04d2e52b9c0cbb81fcf933</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0965544115060043$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0965544115060043$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Gartman, T. N.</creatorcontrib><creatorcontrib>Sovetin, F. S.</creatorcontrib><creatorcontrib>Borovkova, E. A.</creatorcontrib><creatorcontrib>Shvets, V. F.</creatorcontrib><creatorcontrib>Kozlovskii, R. A.</creatorcontrib><creatorcontrib>Loktev, A. S.</creatorcontrib><creatorcontrib>Lebedev, Yu. V.</creatorcontrib><creatorcontrib>Dedov, A. G.</creatorcontrib><creatorcontrib>Moiseev, I. I.</creatorcontrib><title>Partial oxidation of methane to synthesis gas over NdCaCoO4 catalyst: Kinetic modeling of autothermal reforming</title><title>Petroleum chemistry</title><addtitle>Pet. Chem</addtitle><description>Partial oxidation of methane to synthesis gas using a highly selective catalyst based on NdCaCoO
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has been studied, and rate constants have been determined. To determine the kinetic constants in a thin bed of the catalyst with a mass of 0.1 g, a model of isothermal syngas production process has been implemented and objective functions and computational algorithm to minimize the mismatch criterion between calculated and experimental data have been selected. The oxidative methane reforming process has been modeled in the isothermal and autothermal modes. The calculation results for the isothermal mode have been found to agree with experimental data.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Industrial Chemistry/Chemical Engineering</subject><issn>0965-5441</issn><issn>1555-6239</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEqXwAez8A4FxbCc1OxTxEhVFAtaR49itq8RGtovo3-Oo7JBYzeLMuTO6CF0SuCKEsus3EBXnjBHCoQJg9AjNCOe8qEoqjtFswsXET9FZjFsAUhNGZ8i_ypCsHLD_tr1M1jvsDR512kincfI47l3a6GgjXsuI_ZcO-KVvZONXDCuZ5LCP6QY_W6eTVXj0vR6sW08hcpd8VsOY04M2PowZnKMTI4eoL37nHH3c3703j8Vy9fDU3C4LRUueCs1l1Yke-o4SBqKmALWotOyZMlwRIXhFYVEZU0tgfal52QkFqusWxCgjKJ0jcshVwceYz7efwY4y7FsC7dRY-6ex7JQHJ-Zdt9ah3fpdcPnNf6Qf1PdvAw</recordid><startdate>20150701</startdate><enddate>20150701</enddate><creator>Gartman, T. N.</creator><creator>Sovetin, F. S.</creator><creator>Borovkova, E. A.</creator><creator>Shvets, V. F.</creator><creator>Kozlovskii, R. A.</creator><creator>Loktev, A. S.</creator><creator>Lebedev, Yu. V.</creator><creator>Dedov, A. G.</creator><creator>Moiseev, I. I.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20150701</creationdate><title>Partial oxidation of methane to synthesis gas over NdCaCoO4 catalyst: Kinetic modeling of autothermal reforming</title><author>Gartman, T. N. ; Sovetin, F. S. ; Borovkova, E. A. ; Shvets, V. F. ; Kozlovskii, R. A. ; Loktev, A. S. ; Lebedev, Yu. V. ; Dedov, A. G. ; Moiseev, I. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c325t-e5a6b9d0db314097300796ead4cf5c199563086ff7a04d2e52b9c0cbb81fcf933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Industrial Chemistry/Chemical Engineering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gartman, T. N.</creatorcontrib><creatorcontrib>Sovetin, F. S.</creatorcontrib><creatorcontrib>Borovkova, E. A.</creatorcontrib><creatorcontrib>Shvets, V. F.</creatorcontrib><creatorcontrib>Kozlovskii, R. A.</creatorcontrib><creatorcontrib>Loktev, A. S.</creatorcontrib><creatorcontrib>Lebedev, Yu. V.</creatorcontrib><creatorcontrib>Dedov, A. G.</creatorcontrib><creatorcontrib>Moiseev, I. I.</creatorcontrib><collection>CrossRef</collection><jtitle>Petroleum chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gartman, T. N.</au><au>Sovetin, F. S.</au><au>Borovkova, E. A.</au><au>Shvets, V. F.</au><au>Kozlovskii, R. A.</au><au>Loktev, A. S.</au><au>Lebedev, Yu. V.</au><au>Dedov, A. G.</au><au>Moiseev, I. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Partial oxidation of methane to synthesis gas over NdCaCoO4 catalyst: Kinetic modeling of autothermal reforming</atitle><jtitle>Petroleum chemistry</jtitle><stitle>Pet. Chem</stitle><date>2015-07-01</date><risdate>2015</risdate><volume>55</volume><issue>6</issue><spage>455</spage><epage>461</epage><pages>455-461</pages><issn>0965-5441</issn><eissn>1555-6239</eissn><abstract>Partial oxidation of methane to synthesis gas using a highly selective catalyst based on NdCaCoO
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has been studied, and rate constants have been determined. To determine the kinetic constants in a thin bed of the catalyst with a mass of 0.1 g, a model of isothermal syngas production process has been implemented and objective functions and computational algorithm to minimize the mismatch criterion between calculated and experimental data have been selected. The oxidative methane reforming process has been modeled in the isothermal and autothermal modes. The calculation results for the isothermal mode have been found to agree with experimental data.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0965544115060043</doi><tpages>7</tpages></addata></record> |
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| subjects | Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering |
| title | Partial oxidation of methane to synthesis gas over NdCaCoO4 catalyst: Kinetic modeling of autothermal reforming |
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