Development of processes for C4 hydrocarbons separation and 1,3-butadiene purification

Physicochemical substantiation and improved more effective technologies for C 4 -hydrocarbons separation and 1,3-butadiene purification with the help of polar extragents are given, such as compressorless extractive rectification with the use of an intermediate desorbent, extractive rectification of...

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Veröffentlicht in:Theoretical foundations of chemical engineering 2011-12, Vol.45 (6), p.858-867
Hauptverfasser: Pavlov, O. S., Karsakov, S. A., Pavlov, S. Yu
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creator Pavlov, O. S.
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description Physicochemical substantiation and improved more effective technologies for C 4 -hydrocarbons separation and 1,3-butadiene purification with the help of polar extragents are given, such as compressorless extractive rectification with the use of an intermediate desorbent, extractive rectification of the butane- n -butene fraction with preliminary isomerization of 1-butene into 2-butenes, the combined removal of -acetylenes C 4 and methylallene by rectification with a small introduction of the extragent, and the hydration of butenyne in the C 4 fraction and distillation of propyne from it.
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title Development of processes for C4 hydrocarbons separation and 1,3-butadiene purification
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