Interaction between Peroxy Radicals and Acetaldehyde on Solid Surfaces and Its Role in the Oxidation of Aldehydes
Heterogeneous interaction between peroxy radicals and acetaldehyde in a capillary reactor treated with boric acid was studied. The possibility of a reaction occurring between adsorbed peroxy radicals and acetaldehyde was confirmed. Based on a comparison of these data and those obtained for other sur...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2016-04, Vol.90 (4), p.744-747 |
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| container_end_page | 747 |
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| container_issue | 4 |
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| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 90 |
| creator | Vardanyan, I. A. Arustamyan, A. M. Martirosyan, A. S. Tsarukyan, S. V. |
| description | Heterogeneous interaction between peroxy radicals and acetaldehyde in a capillary reactor treated with boric acid was studied. The possibility of a reaction occurring between adsorbed peroxy radicals and acetaldehyde was confirmed. Based on a comparison of these data and those obtained for other surfaces along with the ignition and slow oxidation of aldehydes in reactors with identical surfaces, it was concluded that the oxidation of aldehydes includes not only a homogeneous component but a heterogeneous component as well. |
| doi_str_mv | 10.1134/S0036024416030316 |
| format | Article |
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| ispartof | Russian Journal of Physical Chemistry A, 2016-04, Vol.90 (4), p.744-747 |
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| subjects | Chemical Kinetics and Catalysis Chemistry Chemistry and Materials Science Physical Chemistry |
| title | Interaction between Peroxy Radicals and Acetaldehyde on Solid Surfaces and Its Role in the Oxidation of Aldehydes |
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