Viscosimetry and IR spectroscopy studies of the structure of water in aqueous KBr solutions

Viscosimetry and IR spectroscopy studies of the structure of water in aqueous KBr solutions

The structure of aqueous solutions of KBr was studied by viscosimetry and IR spectroscopy at temperatures of 283.15–333.15 K and concentrations of 0.01–0.07 mole fractions. The results of our experiments were used for calculating the activation parameters of viscous flow, the partial molar volume of...

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2015-07, Vol.89 (7), p.1244-1247
Hauptverfasser: Masimov, E. A., Pashayev, B. G., Hasanov, H. Sh, Hasanov, N. H.
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Structure of Matter and Quantum Chemistry
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container_end_page 1247
container_issue 7
container_start_page 1244
container_title Russian Journal of Physical Chemistry A
container_volume 89
creator Masimov, E. A.
Pashayev, B. G.
Hasanov, H. Sh
Hasanov, N. H.
description The structure of aqueous solutions of KBr was studied by viscosimetry and IR spectroscopy at temperatures of 283.15–333.15 K and concentrations of 0.01–0.07 mole fractions. The results of our experiments were used for calculating the activation parameters of viscous flow, the partial molar volume of KBr in solution, and the energies and lengths of hydrogen bonds between water molecules; the concentration dependences of these parameters were analyzed. The results indicate that KBr desrtroys the structure of water.
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Chemistry and Materials Science
Physical Chemistry
Structure of Matter and Quantum Chemistry
title Viscosimetry and IR spectroscopy studies of the structure of water in aqueous KBr solutions
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