Thermodynamics of the hydrogen bonding of nitrogen-containing cyclic and aromatic compounds with proton donors: The structure-property relationship

Enthalpies of dissolution are measured at infinite dilution of nitrogen-containing cyclic (pyrrolidine, piperidine) and aromatic compounds (aniline, N -methylaniline, N,N -dimethylaniline, N -methylimidazole, pyridine, 2-, 3-, 4-methylpyridine, pyrrole, N -methylpyrrole) in chloroform and dichlorome...

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2014-12, Vol.88 (12), p.2023-2028
Hauptverfasser: Rakipov, I. T., Varfolomeev, M. A., Kirgizov, A. Yu, Solomonov, B. N.
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container_issue 12
container_start_page 2023
container_title Russian Journal of Physical Chemistry A
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creator Rakipov, I. T.
Varfolomeev, M. A.
Kirgizov, A. Yu
Solomonov, B. N.
description Enthalpies of dissolution are measured at infinite dilution of nitrogen-containing cyclic (pyrrolidine, piperidine) and aromatic compounds (aniline, N -methylaniline, N,N -dimethylaniline, N -methylimidazole, pyridine, 2-, 3-, 4-methylpyridine, pyrrole, N -methylpyrrole) in chloroform and dichloromethane, and vice versa ( T = 298.15 K). The enthalpies of hydrogen bonds in the above systems are calculated. Relationships between resulting thermochemical data and the structure of nitrogen-containing cyclic and aromatic compounds are explored.
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Chemistry and Materials Science
Physical Chemistry
title Thermodynamics of the hydrogen bonding of nitrogen-containing cyclic and aromatic compounds with proton donors: The structure-property relationship
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