Using reverse gas-liquid chromatography to determine the thermodynamic functions of sorption in a system of constant volume

A static “ideal gas phase-nonvolatile liquid” system of constant volume in which the volatile component (sorbate) is redistributed is compared to a chromatographic system under conditions corresponding to equilibrium gas-liquid chromatography. The basis for calculating the thermodynamic characterist...

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2014-10, Vol.88 (10), p.1785-1789
Hauptverfasser: Onuchak, L. A., Kudryashov, S. Yu
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container_title Russian Journal of Physical Chemistry A
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creator Onuchak, L. A.
Kudryashov, S. Yu
description A static “ideal gas phase-nonvolatile liquid” system of constant volume in which the volatile component (sorbate) is redistributed is compared to a chromatographic system under conditions corresponding to equilibrium gas-liquid chromatography. The basis for calculating the thermodynamic characteristics of sorption using chromatographic data is described. The standard conditions and way of expressing the constant of interphase sorbate distribution are specified.
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Chemistry and Materials Science
Physical Chemistry
Physical Chemistry of Separation Processes. Chromatography
title Using reverse gas-liquid chromatography to determine the thermodynamic functions of sorption in a system of constant volume
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