Changes in the structure of water in aqueous solutions of acetic acid, depending on concentration and temperature according to densitometry, viscosimetry, and IR spectroscopy data
The structural features of aqueous solutions of acetic acid are studied by means of viscosimetry, densimetry, and IR spectroscopy within the temperature range of 283.15–333.15 K and a concentration range of 0–80%. The results from our experiments are used to calculate the parameters of viscous flow...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2013-06, Vol.87 (6), p.948-951 |
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| container_issue | 6 |
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| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 87 |
| creator | Masimov, E. A. Khasanov, G. Sh Pashaev, B. G. |
| description | The structural features of aqueous solutions of acetic acid are studied by means of viscosimetry, densimetry, and IR spectroscopy within the temperature range of 283.15–333.15 K and a concentration range of 0–80%. The results from our experiments are used to calculate the parameters of viscous flow activation, the structural temperature, the partial molar volume of acetic acid in the solution, the thermal expansion coefficient, and the energies and lengths of the hydrogen bonds between water molecules. The concentration dependences of these parameters are analyzed. Based on the obtained results, we conclude that acetic acid disrupts the structure of water. |
| doi_str_mv | 10.1134/S0036024413060186 |
| format | Article |
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A.</creatorcontrib><creatorcontrib>Khasanov, G. Sh</creatorcontrib><creatorcontrib>Pashaev, B. G.</creatorcontrib><title>Changes in the structure of water in aqueous solutions of acetic acid, depending on concentration and temperature according to densitometry, viscosimetry, and IR spectroscopy data</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>The structural features of aqueous solutions of acetic acid are studied by means of viscosimetry, densimetry, and IR spectroscopy within the temperature range of 283.15–333.15 K and a concentration range of 0–80%. The results from our experiments are used to calculate the parameters of viscous flow activation, the structural temperature, the partial molar volume of acetic acid in the solution, the thermal expansion coefficient, and the energies and lengths of the hydrogen bonds between water molecules. The concentration dependences of these parameters are analyzed. Based on the obtained results, we conclude that acetic acid disrupts the structure of water.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Physical Chemistry</subject><subject>Physical Chemistry of Solutions</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKAzEUhoMoWKsP4C4P0NFkJpnOLKV4KQiCF3A3pMlJm9ImY5JR-ly-oIntTnB1OHz_dxJ-hC4puaK0YtcvhFQ1KRmjFakJbeojNKK8okVTV-_HaJRxkfkpOgthTQhLUTZC37OVsEsI2FgcV4BD9IOMgwfsNP4SEXwm4mMANwQc3GaIxtmQqZAQjUzDqAlW0INVxi6xs1g6K8FGL3IWC6twhG0Pac-HhZTO_0ajS54NJrotRL-b4E8TpAvmsGVx_oxDDzJ6l0i_w0pEcY5OtNgEuDjMMXq7u32dPRSPT_fz2c1jIcumiYWcLhToBS-nBAgTeqFaSWnLuebTVnIuuASYtoImyFRdgiqZEA2TROuybaAaI7q_K9PrwYPuem-2wu86Srrceven9eSUeyekbCrWd2s3eJu--Y_0A5owid8</recordid><startdate>20130601</startdate><enddate>20130601</enddate><creator>Masimov, E. A.</creator><creator>Khasanov, G. Sh</creator><creator>Pashaev, B. G.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20130601</creationdate><title>Changes in the structure of water in aqueous solutions of acetic acid, depending on concentration and temperature according to densitometry, viscosimetry, and IR spectroscopy data</title><author>Masimov, E. A. ; Khasanov, G. Sh ; Pashaev, B. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-c7bdefb5270e04afbd9c11955f579c55a5cee79a104a4d62ed24aa84c0ff298e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Physical Chemistry</topic><topic>Physical Chemistry of Solutions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Masimov, E. 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Chem</stitle><date>2013-06-01</date><risdate>2013</risdate><volume>87</volume><issue>6</issue><spage>948</spage><epage>951</epage><pages>948-951</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>The structural features of aqueous solutions of acetic acid are studied by means of viscosimetry, densimetry, and IR spectroscopy within the temperature range of 283.15–333.15 K and a concentration range of 0–80%. The results from our experiments are used to calculate the parameters of viscous flow activation, the structural temperature, the partial molar volume of acetic acid in the solution, the thermal expansion coefficient, and the energies and lengths of the hydrogen bonds between water molecules. The concentration dependences of these parameters are analyzed. Based on the obtained results, we conclude that acetic acid disrupts the structure of water.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0036024413060186</doi><tpages>4</tpages></addata></record> |
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| ispartof | Russian Journal of Physical Chemistry A, 2013-06, Vol.87 (6), p.948-951 |
| issn | 0036-0244 1531-863X |
| language | eng |
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| source | Springer journals |
| subjects | Chemistry Chemistry and Materials Science Physical Chemistry Physical Chemistry of Solutions |
| title | Changes in the structure of water in aqueous solutions of acetic acid, depending on concentration and temperature according to densitometry, viscosimetry, and IR spectroscopy data |
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