Acid-base properties of the surface of chromatographic sorbents modified by metal acetylacetonates
The acid-base properties of metal acetylacetonates and chromatographic sorbents on the basis of Chromaton N with deposited combined stationary phases from polyethylene glycol (PEG 20M) and nickel(II) and iron(III) acetylacetonates have been investigated by means of pH measurement and Hammett indicat...
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Veröffentlicht in: | Russian Journal of Physical Chemistry A 2012-03, Vol.86 (3), p.463-467 |
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container_title | Russian Journal of Physical Chemistry A |
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creator | Slizhov, Yu. G. Matveev, T. N. Minakova, T. S. |
description | The acid-base properties of metal acetylacetonates and chromatographic sorbents on the basis of Chromaton N with deposited combined stationary phases from polyethylene glycol (PEG 20M) and nickel(II) and iron(III) acetylacetonates have been investigated by means of pH measurement and Hammett indicator adsorption. The change of the acid-base state of the surface of Chromaton N depending on the nature of a metal of the modifying additive, the complex structure, and the deposition method has been demonstrated. |
doi_str_mv | 10.1134/S0036024412030272 |
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subjects | Chemistry Chemistry and Materials Science Physical Chemistry Physical Chemistry of Surface Phenomena |
title | Acid-base properties of the surface of chromatographic sorbents modified by metal acetylacetonates |
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