Intermolecular interactions of polymethacrylic acid with N-alkyl-1,3-propanediamine
The relation between Coulomb and hydrophobic interactions in the development of associative processes is established on the basis of the concentration dependences of pH for binary solutions of anionic polyelectrolyte-polymethacrylic acid and cationic surfactant-N-alkyl-1,3-propanediamine. It is demo...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2012-02, Vol.86 (2), p.223-228 |
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| container_end_page | 228 |
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| container_issue | 2 |
| container_start_page | 223 |
| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 86 |
| creator | Yaremko, Z. M. Burka, O. A. Fedushinskaya, L. B. Soltys, M. N. |
| description | The relation between Coulomb and hydrophobic interactions in the development of associative processes is established on the basis of the concentration dependences of pH for binary solutions of anionic polyelectrolyte-polymethacrylic acid and cationic surfactant-N-alkyl-1,3-propanediamine. It is demonstrated that the criterion for determining the predominant contribution from either Coulomb or hydrophobic interactions is the maximum for the dependence of the pH difference between individual solutions of N-alkyl-1,3-propanediamine and binary solutions of polymethacrylic acid and N-alkyl-1,3-propanediamine on the logarithm of the product of their concentrations. |
| doi_str_mv | 10.1134/S003602441202032X |
| format | Article |
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| ispartof | Russian Journal of Physical Chemistry A, 2012-02, Vol.86 (2), p.223-228 |
| issn | 0036-0244 1531-863X |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Physical Chemistry Physical Chemistry of Solutions |
| title | Intermolecular interactions of polymethacrylic acid with N-alkyl-1,3-propanediamine |
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