The thermodynamic characteristics of complex formation of Cd2+ with N,N-Bis(carboxymethyl)aspartic acid in aqueous solutions at 298.15 K
The equilibrium constants and heats of formation of complexes of N,N-bis(carboxymethyl)aspartic acid (H 4 Y) with Cd 2+ ions at 298.15 K and ionic strengths of 0.2, 0.5, and 1.0 (KNO 3 ) were determined by potentiometric titration and calorimetrically. The thermodynamic characteristics of formation...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2011, Vol.85 (1), p.41-44 |
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| container_title | Russian Journal of Physical Chemistry A |
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| creator | Lytkin, A. I. Chernyavskaya, N. V. Litvinenko, V. E. |
| description | The equilibrium constants and heats of formation of complexes of N,N-bis(carboxymethyl)aspartic acid (H
4
Y) with Cd
2+
ions at 298.15 K and ionic strengths of 0.2, 0.5, and 1.0 (KNO
3
) were determined by potentiometric titration and calorimetrically. The thermodynamic characteristics of formation of the CdY
2−
complex at fixed and zero ionic strength values were calculated. The values obtained were interpreted. |
| doi_str_mv | 10.1134/S0036024410121027 |
| format | Article |
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4
Y) with Cd
2+
ions at 298.15 K and ionic strengths of 0.2, 0.5, and 1.0 (KNO
3
) were determined by potentiometric titration and calorimetrically. The thermodynamic characteristics of formation of the CdY
2−
complex at fixed and zero ionic strength values were calculated. The values obtained were interpreted.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024410121027</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemical Thermodynamics and Thermochemistry ; Chemistry ; Chemistry and Materials Science ; Physical Chemistry</subject><ispartof>Russian Journal of Physical Chemistry A, 2011, Vol.85 (1), p.41-44</ispartof><rights>Pleiades Publishing, Ltd. 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036024410121027$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036024410121027$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Lytkin, A. I.</creatorcontrib><creatorcontrib>Chernyavskaya, N. V.</creatorcontrib><creatorcontrib>Litvinenko, V. E.</creatorcontrib><title>The thermodynamic characteristics of complex formation of Cd2+ with N,N-Bis(carboxymethyl)aspartic acid in aqueous solutions at 298.15 K</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>The equilibrium constants and heats of formation of complexes of N,N-bis(carboxymethyl)aspartic acid (H
4
Y) with Cd
2+
ions at 298.15 K and ionic strengths of 0.2, 0.5, and 1.0 (KNO
3
) were determined by potentiometric titration and calorimetrically. The thermodynamic characteristics of formation of the CdY
2−
complex at fixed and zero ionic strength values were calculated. The values obtained were interpreted.</description><subject>Chemical Thermodynamics and Thermochemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Physical Chemistry</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kM1OwzAQhC0EEqXwANx8BEHK2rFr9wgVf6IqB4rELXIdh7hK4mI7onkDHptEcEPitNLMfKPVIHRKYEJIyq5eANIpUMYIEEqAij00IjwliZymb_toNNjJ4B-ioxA2AKyPshH6WpUGx9L42uVdo2qrsS6VVzoab0O0OmBXYO3qbWV2uHC-VtG6ZhDnOb3AnzaWeHm5TG5sONPKr92uq00su-pcha3yfQNW2ubYNlh9tMa1AQdXtUNJwCpiOpMTwvHTMTooVBXMye8do9e729X8IVk83z_OrxeJJgJiYlIQRgjFCada0SKlkDOlxaxgs5xyLhnVuSQABCTTsuBakPXaSKAyNRxEOkbkp1d7F4I3Rbb1tla-ywhkw5TZnyl7hv4woc8278ZnG9f6pn_zH-gbXlx1kQ</recordid><startdate>2011</startdate><enddate>2011</enddate><creator>Lytkin, A. I.</creator><creator>Chernyavskaya, N. V.</creator><creator>Litvinenko, V. E.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2011</creationdate><title>The thermodynamic characteristics of complex formation of Cd2+ with N,N-Bis(carboxymethyl)aspartic acid in aqueous solutions at 298.15 K</title><author>Lytkin, A. I. ; Chernyavskaya, N. V. ; Litvinenko, V. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c170t-e307e77a5152ca2f320d4ac79f49d255842cd81001084c8f5c71bbe80283e5073</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemical Thermodynamics and Thermochemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lytkin, A. I.</creatorcontrib><creatorcontrib>Chernyavskaya, N. V.</creatorcontrib><creatorcontrib>Litvinenko, V. E.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lytkin, A. I.</au><au>Chernyavskaya, N. V.</au><au>Litvinenko, V. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The thermodynamic characteristics of complex formation of Cd2+ with N,N-Bis(carboxymethyl)aspartic acid in aqueous solutions at 298.15 K</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2011</date><risdate>2011</risdate><volume>85</volume><issue>1</issue><spage>41</spage><epage>44</epage><pages>41-44</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>The equilibrium constants and heats of formation of complexes of N,N-bis(carboxymethyl)aspartic acid (H
4
Y) with Cd
2+
ions at 298.15 K and ionic strengths of 0.2, 0.5, and 1.0 (KNO
3
) were determined by potentiometric titration and calorimetrically. The thermodynamic characteristics of formation of the CdY
2−
complex at fixed and zero ionic strength values were calculated. The values obtained were interpreted.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0036024410121027</doi><tpages>4</tpages></addata></record> |
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| ispartof | Russian Journal of Physical Chemistry A, 2011, Vol.85 (1), p.41-44 |
| issn | 0036-0244 1531-863X |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Chemical Thermodynamics and Thermochemistry Chemistry Chemistry and Materials Science Physical Chemistry |
| title | The thermodynamic characteristics of complex formation of Cd2+ with N,N-Bis(carboxymethyl)aspartic acid in aqueous solutions at 298.15 K |
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