Kinetics and mechanism of 1-phenylethanol oxidation by the system hydrogen peroxide-manganese(IV) binuclear complex-oxalic acid

Hydrogen peroxide was found to oxidize 1 -phenylethanol to acetophenone in acetonitrile homogeneous solution efficiently at room temperature in the presence of a dimeric complex of manganese (IV) [LMn(O) 3 MnL](PF 6 ) 2 (where L = 1,4,7-trimethyl-1,4,7-triazacyclononane) as the catalyst and oxalic a...

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Veröffentlicht in:	Russian Journal of Physical Chemistry A 2010-09, Vol.84 (9), p.1502-1505
Hauptverfasser:	Kozlov, Yu. N., Shul’pina, L. S., Strelkova, T. V., Shul’pin, G. B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Kinetics and Catalysis Chemistry Chemistry and Materials Science Physical Chemistry
Online-Zugang:	Volltext
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