Reactions of β-Dioxo Compounds with Hydrogen Peroxide at Low Temperatures
The paper presents the results obtained for the malonic aldehyde—hydrogen peroxide and β-oxobutanal—hydrogen peroxide systems. The systems were studied by IR spectroscopy in xenon matrices. The potential energy surfaces and vibrational spectra of the molecules that could occur in these systems were...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry 2008, Vol.82 (4), p.558-564 |
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| container_end_page | 564 |
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| container_issue | 4 |
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| container_title | Russian Journal of Physical Chemistry |
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| creator | Serebrennikov, L. V. Golovkin, A. V. Davlyatshin, D. I. Shevel’kov, V. F. |
| description | The paper presents the results obtained for the malonic aldehyde—hydrogen peroxide and β-oxobutanal—hydrogen peroxide systems. The systems were studied by IR spectroscopy in xenon matrices. The potential energy surfaces and vibrational spectra of the molecules that could occur in these systems were calculated quantum-chemically. As distinct from similar systems with monoaldehydes and α-dioxo compounds, the first stage of the reactions that occurred in the systems under consideration involved the decomposition of hydrogen peroxide with the formation of atomic oxygen, whose secondary reactions determined the set of reaction products. |
| doi_str_mv | 10.1134/S0036024408040092 |
| format | Article |
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| identifier | ISSN: 0036-0244 |
| ispartof | Russian Journal of Physical Chemistry, 2008, Vol.82 (4), p.558-564 |
| issn | 0036-0244 1531-863X |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Chemical Kinetics and Catalysis Chemistry Chemistry and Materials Science Physical Chemistry |
| title | Reactions of β-Dioxo Compounds with Hydrogen Peroxide at Low Temperatures |
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