Chemical Nuclear Polarization of Biradicals Created by Photolysis of Cyclic Aliphatic Ketones in the Gas Phase

Chemical nuclear polarization (CNP) of short-lived biradicals created in the photolysis of cyclic ketones in the gas phase with a buffer gas of CDCl 3 molecules was studied theoretically and experimentally. The magnetoresonance and kinetic parameters were proposed for the biradicals. The experimenta...

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Veröffentlicht in:Russian Journal of Physical Chemistry 2008-02, Vol.82 (2), p.298-302
Hauptverfasser: Obynochnyia, A. A., Purtovb, P. A., Salikhova, K. M.
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Sprache:eng
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