Thermodynamic characteristics of complexation between Ho3+ and ethylenediamine-N,N'-disuccinic acid in aqueous solutions at 298.15 K
The thermodynamic characteristics of complexation between ethylenediamine- N , N '-disuccinic acid (H 4 Y; EDDA) and Ho 3+ ion were determined calorimetrically and potentiometrically at 298.15 K and ionic strengths of 0.1, 0.5, 1.0, and 1.5 (KNO 3 ). The log K , Δ r G , Δ r H , and Δ r S values...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2016-04, Vol.61 (4), p.526-530 |
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| container_title | Russian journal of inorganic chemistry |
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| creator | Lytkin, A. I. Chernyavskaya, N. V. Chernov, A. S. Litvinenko, V. E. |
| description | The thermodynamic characteristics of complexation between ethylenediamine-
N
,
N
'-disuccinic acid (H
4
Y; EDDA) and Ho
3+
ion were determined calorimetrically and potentiometrically at 298.15 K and ionic strengths of 0.1, 0.5, 1.0, and 1.5 (KNO
3
). The log
K
, Δ
r
G
, Δ
r
H
, and Δ
r
S
values for the formation of HoY
–
and HOHY complexes were calculated at the studied and zero ionic strength values. The changes in thermodynamic parameters of the reactions are discussed. |
| doi_str_mv | 10.1134/S0036023616040124 |
| format | Article |
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N
,
N
'-disuccinic acid (H
4
Y; EDDA) and Ho
3+
ion were determined calorimetrically and potentiometrically at 298.15 K and ionic strengths of 0.1, 0.5, 1.0, and 1.5 (KNO
3
). The log
K
, Δ
r
G
, Δ
r
H
, and Δ
r
S
values for the formation of HoY
–
and HOHY complexes were calculated at the studied and zero ionic strength values. The changes in thermodynamic parameters of the reactions are discussed.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023616040124</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Physical Chemistry of Solutions</subject><ispartof>Russian journal of inorganic chemistry, 2016-04, Vol.61 (4), p.526-530</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c218t-24b86b57a385d28cc6b99f8ffd2ce77fc7bb3915c5971d87f15186c9f7ee9bd53</citedby><cites>FETCH-LOGICAL-c218t-24b86b57a385d28cc6b99f8ffd2ce77fc7bb3915c5971d87f15186c9f7ee9bd53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023616040124$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023616040124$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Lytkin, A. I.</creatorcontrib><creatorcontrib>Chernyavskaya, N. V.</creatorcontrib><creatorcontrib>Chernov, A. S.</creatorcontrib><creatorcontrib>Litvinenko, V. E.</creatorcontrib><title>Thermodynamic characteristics of complexation between Ho3+ and ethylenediamine-N,N'-disuccinic acid in aqueous solutions at 298.15 K</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The thermodynamic characteristics of complexation between ethylenediamine-
N
,
N
'-disuccinic acid (H
4
Y; EDDA) and Ho
3+
ion were determined calorimetrically and potentiometrically at 298.15 K and ionic strengths of 0.1, 0.5, 1.0, and 1.5 (KNO
3
). The log
K
, Δ
r
G
, Δ
r
H
, and Δ
r
S
values for the formation of HoY
–
and HOHY complexes were calculated at the studied and zero ionic strength values. The changes in thermodynamic parameters of the reactions are discussed.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry of Solutions</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kDtPwzAUhS0EEqXwA9i8MUCKH3k4I6qAIqoyUObIsa-pq8QudiLozg8nUdmQmO5w7vfp6CB0ScmMUp7evhLCc8J4TnOSEsrSIzShGaeJyCk_RpMxTsb8FJ3FuCUkTUkhJuh7vYHQer13srUKq40MUnUQbOysitgbrHy7a-BLdtY7XEP3CeDwwvNrLJ3G0G32DTjQduAdJKub1VWibeyVsm4QSmU1tg7Ljx58H3H0TT-aIpYdZqWY0Qw_n6MTI5sIF793it4e7tfzRbJ8eXya3y0TxajoEpbWIq-zQnKRaSaUyuuyNMIYzRQUhVFFXfOSZiorC6pFYWhGRa5KUwCUtc74FNGDVwUfYwBT7YJtZdhXlFTjjNWfGQeGHZg4_Lp3CNXW98ENNf-BfgAVjnWf</recordid><startdate>20160401</startdate><enddate>20160401</enddate><creator>Lytkin, A. I.</creator><creator>Chernyavskaya, N. V.</creator><creator>Chernov, A. S.</creator><creator>Litvinenko, V. E.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160401</creationdate><title>Thermodynamic characteristics of complexation between Ho3+ and ethylenediamine-N,N'-disuccinic acid in aqueous solutions at 298.15 K</title><author>Lytkin, A. I. ; Chernyavskaya, N. V. ; Chernov, A. S. ; Litvinenko, V. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c218t-24b86b57a385d28cc6b99f8ffd2ce77fc7bb3915c5971d87f15186c9f7ee9bd53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry of Solutions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lytkin, A. I.</creatorcontrib><creatorcontrib>Chernyavskaya, N. V.</creatorcontrib><creatorcontrib>Chernov, A. S.</creatorcontrib><creatorcontrib>Litvinenko, V. E.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lytkin, A. I.</au><au>Chernyavskaya, N. V.</au><au>Chernov, A. S.</au><au>Litvinenko, V. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermodynamic characteristics of complexation between Ho3+ and ethylenediamine-N,N'-disuccinic acid in aqueous solutions at 298.15 K</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2016-04-01</date><risdate>2016</risdate><volume>61</volume><issue>4</issue><spage>526</spage><epage>530</epage><pages>526-530</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The thermodynamic characteristics of complexation between ethylenediamine-
N
,
N
'-disuccinic acid (H
4
Y; EDDA) and Ho
3+
ion were determined calorimetrically and potentiometrically at 298.15 K and ionic strengths of 0.1, 0.5, 1.0, and 1.5 (KNO
3
). The log
K
, Δ
r
G
, Δ
r
H
, and Δ
r
S
values for the formation of HoY
–
and HOHY complexes were calculated at the studied and zero ionic strength values. The changes in thermodynamic parameters of the reactions are discussed.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023616040124</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0236 |
| ispartof | Russian journal of inorganic chemistry, 2016-04, Vol.61 (4), p.526-530 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S0036023616040124 |
| source | SpringerLink Journals |
| subjects | Chemistry Chemistry and Materials Science Inorganic Chemistry Physical Chemistry of Solutions |
| title | Thermodynamic characteristics of complexation between Ho3+ and ethylenediamine-N,N'-disuccinic acid in aqueous solutions at 298.15 K |
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