Copper(II), iron(III), and chromium(III) complexes with 5,10-dioxo-4,5,9,10-tetrahydro-4,9-diazapyrene derivatives
Six copper(II), iron(III), and chromium(III) complexes with 5,10-dioxo-4,5,9,10-tetrahydro-4,9-diazapyrene derivatives (H₂L¹-H₂L³) have been synthesized and studied by physical methods (IR and electronic absorption spectroscopy, quantum-chemical calculations). The composition of the complexes has be...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2010, Vol.55 (5), p.709-713 |
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| container_title | Russian journal of inorganic chemistry |
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| creator | Kovalchukova, O. V Tsegel'nik, O. A Strashnov, P. V Zaitsev, B. E Strashnova, S. B Volyanski, O. V Kobrakov, K. E |
| description | Six copper(II), iron(III), and chromium(III) complexes with 5,10-dioxo-4,5,9,10-tetrahydro-4,9-diazapyrene derivatives (H₂L¹-H₂L³) have been synthesized and studied by physical methods (IR and electronic absorption spectroscopy, quantum-chemical calculations). The composition of the complexes has been determined and their stability constants in aqueous dimethylformamide solutions have been calculated. The energy characteristics, electronic structure and geometry of isolated diazapyrenes and their tautomeric forms have been calculated by the PM6 method, and their complexes have been modeled. |
| doi_str_mv | 10.1134/S0036023610050098 |
| format | Article |
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| subjects | Chemistry Chemistry and Materials Science Coordination Compounds Inorganic Chemistry |
| title | Copper(II), iron(III), and chromium(III) complexes with 5,10-dioxo-4,5,9,10-tetrahydro-4,9-diazapyrene derivatives |
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