Kinetics of urethane formation from isophorone diisocyanate: The alcohol nature effect
The kinetics of the noncatalytic reactions of isophorone diisocyanate with n -propanol, isopropanol, 1,3-diazidopropan-2-ol, propargyl alcohol, and phenol in toluene in the temperature range from 20 to 90°C at the stoichiometric ratio of reactive groups has been investigated by IR spectroscopy. The...
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| Veröffentlicht in: | Kinetics and catalysis 2016-05, Vol.57 (3), p.319-325 |
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| container_title | Kinetics and catalysis |
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| creator | Karpov, S. V. Lodygina, V. P. Komratova, V. V. Dzhalmukhanova, A. S. Malkov, G. V. Badamshina, E. R. |
| description | The kinetics of the noncatalytic reactions of isophorone diisocyanate with
n
-propanol, isopropanol, 1,3-diazidopropan-2-ol, propargyl alcohol, and phenol in toluene in the temperature range from 20 to 90°C at the stoichiometric ratio of reactive groups has been investigated by IR spectroscopy. The apparent rate constants for the reactions of the aliphatic and cycloaliphatic isocyanate groups of isophorone diisocyanate with all of the alcohols have been measured. The activation parameters of the reactions of isophorone diisocyanate with
n
-propanol, isopropanol, and 1,3-diazidopropan-2-ol have been determined. The data obtained are considered in terms of the alcohol structure and molecular organization of solutions. |
| doi_str_mv | 10.1134/S0023158416030058 |
| format | Article |
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n
-propanol, isopropanol, 1,3-diazidopropan-2-ol, propargyl alcohol, and phenol in toluene in the temperature range from 20 to 90°C at the stoichiometric ratio of reactive groups has been investigated by IR spectroscopy. The apparent rate constants for the reactions of the aliphatic and cycloaliphatic isocyanate groups of isophorone diisocyanate with all of the alcohols have been measured. The activation parameters of the reactions of isophorone diisocyanate with
n
-propanol, isopropanol, and 1,3-diazidopropan-2-ol have been determined. The data obtained are considered in terms of the alcohol structure and molecular organization of solutions.</description><identifier>ISSN: 0023-1584</identifier><identifier>EISSN: 1608-3210</identifier><identifier>DOI: 10.1134/S0023158416030058</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Catalysis ; Chemistry ; Chemistry and Materials Science ; Physical Chemistry</subject><ispartof>Kinetics and catalysis, 2016-05, Vol.57 (3), p.319-325</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c325t-6f5f3dbfc8cf012949648928524d8da5bf59b803111f55459dc2f023da02a9b3</citedby><cites>FETCH-LOGICAL-c325t-6f5f3dbfc8cf012949648928524d8da5bf59b803111f55459dc2f023da02a9b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0023158416030058$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0023158416030058$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Karpov, S. V.</creatorcontrib><creatorcontrib>Lodygina, V. P.</creatorcontrib><creatorcontrib>Komratova, V. V.</creatorcontrib><creatorcontrib>Dzhalmukhanova, A. S.</creatorcontrib><creatorcontrib>Malkov, G. V.</creatorcontrib><creatorcontrib>Badamshina, E. R.</creatorcontrib><title>Kinetics of urethane formation from isophorone diisocyanate: The alcohol nature effect</title><title>Kinetics and catalysis</title><addtitle>Kinet Catal</addtitle><description>The kinetics of the noncatalytic reactions of isophorone diisocyanate with
n
-propanol, isopropanol, 1,3-diazidopropan-2-ol, propargyl alcohol, and phenol in toluene in the temperature range from 20 to 90°C at the stoichiometric ratio of reactive groups has been investigated by IR spectroscopy. The apparent rate constants for the reactions of the aliphatic and cycloaliphatic isocyanate groups of isophorone diisocyanate with all of the alcohols have been measured. The activation parameters of the reactions of isophorone diisocyanate with
n
-propanol, isopropanol, and 1,3-diazidopropan-2-ol have been determined. The data obtained are considered in terms of the alcohol structure and molecular organization of solutions.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Physical Chemistry</subject><issn>0023-1584</issn><issn>1608-3210</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEqXwAez8A4EZPyqbHap4iUosiNhGjuMhqdq4stNF_x5XZYfEah53zmjmMnaLcIco1f0ngJCojcIFSABtztispKaSAuGczY5yddQv2VXOawBQqOyMfb0PY5gGn3kkvk9h6t0YOMW0ddMQR04pbvmQ466PKRalG0rhD250U3jgdR-42_jYxw0vncLzQBT8dM0uyG1yuPmNc1Y_P9XL12r18fK2fFxVXgo9VQvSJLuWvPEEKKyyC2WsMFqoznROt6Rta0AiImmttO28oPJJ50A428o5w9Nan2LOKVCzS8PWpUOD0Bx9af74UhhxYnKZHb9DatZxn8Zy5T_QD0FAZUs</recordid><startdate>20160501</startdate><enddate>20160501</enddate><creator>Karpov, S. V.</creator><creator>Lodygina, V. P.</creator><creator>Komratova, V. V.</creator><creator>Dzhalmukhanova, A. S.</creator><creator>Malkov, G. V.</creator><creator>Badamshina, E. R.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160501</creationdate><title>Kinetics of urethane formation from isophorone diisocyanate: The alcohol nature effect</title><author>Karpov, S. V. ; Lodygina, V. P. ; Komratova, V. V. ; Dzhalmukhanova, A. S. ; Malkov, G. V. ; Badamshina, E. R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c325t-6f5f3dbfc8cf012949648928524d8da5bf59b803111f55459dc2f023da02a9b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karpov, S. V.</creatorcontrib><creatorcontrib>Lodygina, V. P.</creatorcontrib><creatorcontrib>Komratova, V. V.</creatorcontrib><creatorcontrib>Dzhalmukhanova, A. S.</creatorcontrib><creatorcontrib>Malkov, G. V.</creatorcontrib><creatorcontrib>Badamshina, E. R.</creatorcontrib><collection>CrossRef</collection><jtitle>Kinetics and catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karpov, S. V.</au><au>Lodygina, V. P.</au><au>Komratova, V. V.</au><au>Dzhalmukhanova, A. S.</au><au>Malkov, G. V.</au><au>Badamshina, E. R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetics of urethane formation from isophorone diisocyanate: The alcohol nature effect</atitle><jtitle>Kinetics and catalysis</jtitle><stitle>Kinet Catal</stitle><date>2016-05-01</date><risdate>2016</risdate><volume>57</volume><issue>3</issue><spage>319</spage><epage>325</epage><pages>319-325</pages><issn>0023-1584</issn><eissn>1608-3210</eissn><abstract>The kinetics of the noncatalytic reactions of isophorone diisocyanate with
n
-propanol, isopropanol, 1,3-diazidopropan-2-ol, propargyl alcohol, and phenol in toluene in the temperature range from 20 to 90°C at the stoichiometric ratio of reactive groups has been investigated by IR spectroscopy. The apparent rate constants for the reactions of the aliphatic and cycloaliphatic isocyanate groups of isophorone diisocyanate with all of the alcohols have been measured. The activation parameters of the reactions of isophorone diisocyanate with
n
-propanol, isopropanol, and 1,3-diazidopropan-2-ol have been determined. The data obtained are considered in terms of the alcohol structure and molecular organization of solutions.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0023158416030058</doi><tpages>7</tpages></addata></record> |
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| title | Kinetics of urethane formation from isophorone diisocyanate: The alcohol nature effect |
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