Regularities in the consumption of the initial reactants in various kinetic regimes

Using hydrogen oxidation as an example, it is demonstrated that, when gas ignition is prevented by means of inhibition, there is practically no consumption of the initial reactants because reaction chains do not form for lack of time and the rates of intermolecular reactions are insignificant. When...

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Veröffentlicht in:Kinetics and catalysis 2016, Vol.57 (1), p.17-21
Hauptverfasser: Azatyan, V. V., Balayan, G. V., Prokopenko, V. M., Chapysheva, N. V.
Format: Artikel
Sprache:eng
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Zusammenfassung:Using hydrogen oxidation as an example, it is demonstrated that, when gas ignition is prevented by means of inhibition, there is practically no consumption of the initial reactants because reaction chains do not form for lack of time and the rates of intermolecular reactions are insignificant. When the propagating flame and detonation wave are partially suppressed, the inhibitor is consumed only in chain termination reactions involving reactive intermediate species. Oxygen is additionally consumed in its reactions with products of incomplete inhibitor conversion.
ISSN:0023-1584
1608-3210
DOI:10.1134/S0023158416010018