NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II)
The structures of two Al(III) and Fe(III) β-diketonates with a γ-substituted ligand are studied by single crystal X-ray diffraction at 150(2) K. Crystallographic data for Al(γ-Me-hd) 3 ( I ) are: space group , a = 10.855(1) Å, b = 11.129(1) Å, с = 11.894(1) Å, α = 85.634(3)°, F0200062 = 73.118(3)...
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| Veröffentlicht in: | Journal of structural chemistry 2020-10, Vol.61 (10), p.1615-1623 |
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| container_issue | 10 |
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| container_title | Journal of structural chemistry |
| container_volume | 61 |
| creator | Stabnikov, P. A. Alferova, N. I. Korolkov, I. V. Pervukhina, N. V. Trubin, S. V. Babailov, S. P. Turgambaeva, A. E. |
| description | The structures of two Al(III) and Fe(III) β-diketonates with a γ-substituted ligand are studied by single crystal X-ray diffraction at 150(2) K. Crystallographic data for Al(γ-Me-hd)
3
(
I
) are: space group
,
a
= 10.855(1) Å,
b
= 11.129(1) Å,
с
= 11.894(1) Å, α = 85.634(3)°, F0200062 = 73.118(3)°, γ = 66.771(3)°,
V
= 1262.2(2) Å
3
,
Z
= 2,
R
1
= 0.0438. For Fe(γ-Me-hd)
3
(
II
): space group
P
2
1
/
с
,
a
= 10.0374(5) Å,
b
= 17.0798(7) Å,
с
= 15.7213(6) Å, F0200062 = 107.459(1)°,
V
= 2571.1(2) Å
3
,
Z
= 4,
R
1
= 0.0364. Compounds
I
and
II
are isotypical because their molecules have the same structure but crystallize in different crystal systems. The crystal structures of
I
and
II
are molecular and consist of discrete
M
(γ-Me-hd)
3
(
M
= Al, Fe) molecules. Thermogravimetric studies show that complexes
I
and
II
are similarly volatile. For Cu(γ-Me-hd)
2
complex (
III
) the saturated vapor pressure is measured by the Knudsen method in the temperature range 100-150 °C. Sublimation thermodynamic parameters are found and vapor thermolysis is investigated. |
| doi_str_mv | 10.1134/S0022476620100145 |
| format | Article |
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3
(
I
) are: space group
,
a
= 10.855(1) Å,
b
= 11.129(1) Å,
с
= 11.894(1) Å, α = 85.634(3)°, F0200062 = 73.118(3)°, γ = 66.771(3)°,
V
= 1262.2(2) Å
3
,
Z
= 2,
R
1
= 0.0438. For Fe(γ-Me-hd)
3
(
II
): space group
P
2
1
/
с
,
a
= 10.0374(5) Å,
b
= 17.0798(7) Å,
с
= 15.7213(6) Å, F0200062 = 107.459(1)°,
V
= 2571.1(2) Å
3
,
Z
= 4,
R
1
= 0.0364. Compounds
I
and
II
are isotypical because their molecules have the same structure but crystallize in different crystal systems. The crystal structures of
I
and
II
are molecular and consist of discrete
M
(γ-Me-hd)
3
(
M
= Al, Fe) molecules. Thermogravimetric studies show that complexes
I
and
II
are similarly volatile. For Cu(γ-Me-hd)
2
complex (
III
) the saturated vapor pressure is measured by the Knudsen method in the temperature range 100-150 °C. Sublimation thermodynamic parameters are found and vapor thermolysis is investigated.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476620100145</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2020-10, Vol.61 (10), p.1615-1623</ispartof><rights>Pleiades Publishing, Ltd. 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-f4bc1cd6c1e6098a6326815ce7ff4c5069e39a01eb244be0a66ed37ad8b930393</citedby><cites>FETCH-LOGICAL-c288t-f4bc1cd6c1e6098a6326815ce7ff4c5069e39a01eb244be0a66ed37ad8b930393</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476620100145$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476620100145$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Stabnikov, P. A.</creatorcontrib><creatorcontrib>Alferova, N. I.</creatorcontrib><creatorcontrib>Korolkov, I. V.</creatorcontrib><creatorcontrib>Pervukhina, N. V.</creatorcontrib><creatorcontrib>Trubin, S. V.</creatorcontrib><creatorcontrib>Babailov, S. P.</creatorcontrib><creatorcontrib>Turgambaeva, A. E.</creatorcontrib><title>NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II)</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>The structures of two Al(III) and Fe(III) β-diketonates with a γ-substituted ligand are studied by single crystal X-ray diffraction at 150(2) K. Crystallographic data for Al(γ-Me-hd)
3
(
I
) are: space group
,
a
= 10.855(1) Å,
b
= 11.129(1) Å,
с
= 11.894(1) Å, α = 85.634(3)°, F0200062 = 73.118(3)°, γ = 66.771(3)°,
V
= 1262.2(2) Å
3
,
Z
= 2,
R
1
= 0.0438. For Fe(γ-Me-hd)
3
(
II
): space group
P
2
1
/
с
,
a
= 10.0374(5) Å,
b
= 17.0798(7) Å,
с
= 15.7213(6) Å, F0200062 = 107.459(1)°,
V
= 2571.1(2) Å
3
,
Z
= 4,
R
1
= 0.0364. Compounds
I
and
II
are isotypical because their molecules have the same structure but crystallize in different crystal systems. The crystal structures of
I
and
II
are molecular and consist of discrete
M
(γ-Me-hd)
3
(
M
= Al, Fe) molecules. Thermogravimetric studies show that complexes
I
and
II
are similarly volatile. For Cu(γ-Me-hd)
2
complex (
III
) the saturated vapor pressure is measured by the Knudsen method in the temperature range 100-150 °C. Sublimation thermodynamic parameters are found and vapor thermolysis is investigated.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kM9Og0AQxjdGE7H6AN72aBNXZ_-w7B6xgBIbOLDEI4FlMTa1NWAPvpa-R59JSHsz8TQz-eY33-RD6JrCHaVc3BcAjIlASgYUgAr_BHnUDzhRQaBPkTfJZNLP0cUwrABAKy09FGbxC97_kKJ8KExqShNHeP9NovQ5NnkWmrjAeYLD9U2apvNbnLhjE2YRXuzGYX6Jzrp6PbirY52hMonN4oks88d0ES6JZUp9kk40ltpWWurk6F1LzqSivnVB1wnrg9SO6xqoa5gQjYNaStfyoG5VozlwzWeIHu7afjsMveuqj_7tve6_KgrVlEH1J4ORYQdmGHc3r66vVttdvxnf_Af6BciaWDc</recordid><startdate>20201001</startdate><enddate>20201001</enddate><creator>Stabnikov, P. A.</creator><creator>Alferova, N. I.</creator><creator>Korolkov, I. V.</creator><creator>Pervukhina, N. V.</creator><creator>Trubin, S. V.</creator><creator>Babailov, S. P.</creator><creator>Turgambaeva, A. E.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20201001</creationdate><title>NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II)</title><author>Stabnikov, P. A. ; Alferova, N. I. ; Korolkov, I. V. ; Pervukhina, N. V. ; Trubin, S. V. ; Babailov, S. P. ; Turgambaeva, A. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-f4bc1cd6c1e6098a6326815ce7ff4c5069e39a01eb244be0a66ed37ad8b930393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stabnikov, P. A.</creatorcontrib><creatorcontrib>Alferova, N. I.</creatorcontrib><creatorcontrib>Korolkov, I. V.</creatorcontrib><creatorcontrib>Pervukhina, N. V.</creatorcontrib><creatorcontrib>Trubin, S. V.</creatorcontrib><creatorcontrib>Babailov, S. P.</creatorcontrib><creatorcontrib>Turgambaeva, A. E.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stabnikov, P. A.</au><au>Alferova, N. I.</au><au>Korolkov, I. V.</au><au>Pervukhina, N. V.</au><au>Trubin, S. V.</au><au>Babailov, S. P.</au><au>Turgambaeva, A. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II)</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2020-10-01</date><risdate>2020</risdate><volume>61</volume><issue>10</issue><spage>1615</spage><epage>1623</epage><pages>1615-1623</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>The structures of two Al(III) and Fe(III) β-diketonates with a γ-substituted ligand are studied by single crystal X-ray diffraction at 150(2) K. Crystallographic data for Al(γ-Me-hd)
3
(
I
) are: space group
,
a
= 10.855(1) Å,
b
= 11.129(1) Å,
с
= 11.894(1) Å, α = 85.634(3)°, F0200062 = 73.118(3)°, γ = 66.771(3)°,
V
= 1262.2(2) Å
3
,
Z
= 2,
R
1
= 0.0438. For Fe(γ-Me-hd)
3
(
II
): space group
P
2
1
/
с
,
a
= 10.0374(5) Å,
b
= 17.0798(7) Å,
с
= 15.7213(6) Å, F0200062 = 107.459(1)°,
V
= 2571.1(2) Å
3
,
Z
= 4,
R
1
= 0.0364. Compounds
I
and
II
are isotypical because their molecules have the same structure but crystallize in different crystal systems. The crystal structures of
I
and
II
are molecular and consist of discrete
M
(γ-Me-hd)
3
(
M
= Al, Fe) molecules. Thermogravimetric studies show that complexes
I
and
II
are similarly volatile. For Cu(γ-Me-hd)
2
complex (
III
) the saturated vapor pressure is measured by the Knudsen method in the temperature range 100-150 °C. Sublimation thermodynamic parameters are found and vapor thermolysis is investigated.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476620100145</doi><tpages>9</tpages></addata></record> |
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| source | SpringerLink Journals |
| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Inorganic Chemistry Molecular Optical and Plasma Physics Physical Chemistry Solid State Physics |
| title | NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II) |
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