Crystal structures of two enantiomorphous 2-ethylpiperazinediium hexaaquacopper sulfates [(R or S)-C5H14N2][Cu(H2O)6](SO4)2
Two new non-centrosymmetric copper sulfates are synthesized under slow evaporation conditions through the use of enantiomorphically pure sources of either (R)-2-methylpiperazine or (S)-2-methylpiperazine. Both crystallize in the non-centrosymmetric P 2 1 space group, crystal data for [(R)-C 5 H 14 N...
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| Veröffentlicht in: | Journal of structural chemistry 2012-03, Vol.53 (2), p.334-340 |
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| creator | Hajlaoui, F. Naïli, H. Yahyaoui, S. Mhiri, T. Bataille, T. |
| description | Two new non-centrosymmetric copper sulfates are synthesized under slow evaporation conditions through the use of enantiomorphically pure sources of either (R)-2-methylpiperazine or (S)-2-methylpiperazine. Both crystallize in the non-centrosymmetric
P
2
1
space group, crystal data for [(R)-C
5
H
14
N
2
][Cu(H
2
O)
6
](SO
4
)
2
(
I
),
a
= 6.5276(2) Å,
b
= 11.1955(3) Å,
c
= 12.4559(4) Å, β = 101.196(2)°,
Z
= 2,
V
= 892.95(5) Å
3
and [(S)-C
5
H
14
N
2
][Cu(H
2
O)
6
](SO
4
)
2
(
II
),
a
= 6.5188(2) Å,
b
= 11.1786(2) Å,
c
= 12.4365(3) Å, β = 101.205(1)°,
Z
= 2,
V
= 888.99(4) Å
3
. The three-dimensional structure networks for these compounds consist of isolated [Cu(H
2
O)
6
]
2+
and [(R)-C
5
H
14
N
2
]
2+
or [(S)-C
5
H
14
N
2
]
2+
cations and SO
4
2−
anions linked only by hydrogen bonds. The Cu atom is in a slightly distorted octahedral coordination environment. The crystal packings are influenced by cation-to-anion N-H…O and OW-H…O hydrogen bonds leading to an open framework structures. |
| doi_str_mv | 10.1134/S0022476612020187 |
| format | Article |
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P
2
1
space group, crystal data for [(R)-C
5
H
14
N
2
][Cu(H
2
O)
6
](SO
4
)
2
(
I
),
a
= 6.5276(2) Å,
b
= 11.1955(3) Å,
c
= 12.4559(4) Å, β = 101.196(2)°,
Z
= 2,
V
= 892.95(5) Å
3
and [(S)-C
5
H
14
N
2
][Cu(H
2
O)
6
](SO
4
)
2
(
II
),
a
= 6.5188(2) Å,
b
= 11.1786(2) Å,
c
= 12.4365(3) Å, β = 101.205(1)°,
Z
= 2,
V
= 888.99(4) Å
3
. The three-dimensional structure networks for these compounds consist of isolated [Cu(H
2
O)
6
]
2+
and [(R)-C
5
H
14
N
2
]
2+
or [(S)-C
5
H
14
N
2
]
2+
cations and SO
4
2−
anions linked only by hydrogen bonds. The Cu atom is in a slightly distorted octahedral coordination environment. The crystal packings are influenced by cation-to-anion N-H…O and OW-H…O hydrogen bonds leading to an open framework structures.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476612020187</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2012-03, Vol.53 (2), p.334-340</ispartof><rights>Pleiades Publishing, Ltd. 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2037-e1a7c5497801718cfe4dd2482a38d99e2eeb2aa532622e24b5c14b09f3f1f5573</citedby><cites>FETCH-LOGICAL-c2037-e1a7c5497801718cfe4dd2482a38d99e2eeb2aa532622e24b5c14b09f3f1f5573</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476612020187$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476612020187$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Hajlaoui, F.</creatorcontrib><creatorcontrib>Naïli, H.</creatorcontrib><creatorcontrib>Yahyaoui, S.</creatorcontrib><creatorcontrib>Mhiri, T.</creatorcontrib><creatorcontrib>Bataille, T.</creatorcontrib><title>Crystal structures of two enantiomorphous 2-ethylpiperazinediium hexaaquacopper sulfates [(R or S)-C5H14N2][Cu(H2O)6](SO4)2</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>Two new non-centrosymmetric copper sulfates are synthesized under slow evaporation conditions through the use of enantiomorphically pure sources of either (R)-2-methylpiperazine or (S)-2-methylpiperazine. Both crystallize in the non-centrosymmetric
P
2
1
space group, crystal data for [(R)-C
5
H
14
N
2
][Cu(H
2
O)
6
](SO
4
)
2
(
I
),
a
= 6.5276(2) Å,
b
= 11.1955(3) Å,
c
= 12.4559(4) Å, β = 101.196(2)°,
Z
= 2,
V
= 892.95(5) Å
3
and [(S)-C
5
H
14
N
2
][Cu(H
2
O)
6
](SO
4
)
2
(
II
),
a
= 6.5188(2) Å,
b
= 11.1786(2) Å,
c
= 12.4365(3) Å, β = 101.205(1)°,
Z
= 2,
V
= 888.99(4) Å
3
. The three-dimensional structure networks for these compounds consist of isolated [Cu(H
2
O)
6
]
2+
and [(R)-C
5
H
14
N
2
]
2+
or [(S)-C
5
H
14
N
2
]
2+
cations and SO
4
2−
anions linked only by hydrogen bonds. The Cu atom is in a slightly distorted octahedral coordination environment. The crystal packings are influenced by cation-to-anion N-H…O and OW-H…O hydrogen bonds leading to an open framework structures.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLwzAYhoMoOKc_wFuO26GafE2b9ihFN2E4cHoao2TtF9fRNTVp0Omft2PeBE_f4f2el5eHkGvObjgPxe2CMQAh45gDA8YTeUIGPJJhkEiZnpLBIQ4O-Tm5cG7LGEuTNB6Q78zuXadq6jrri85bdNRo2n0Yio1qusrsjG03xjsKAXabfd1WLVr1VTVYVpXf0Q1-KvXuVWHaPqDO11p1fcty9EyNpYtxkEVTLp5gtcz8aArzcbwaLeZiDJfkTKva4dXvHZLXh_uXbBrM5pPH7G4WFMBCGSBXsohEKhPGJU8KjaIsQSSgwqRMUwTENSgVhRADIIh1VHCxZqkONddR72BI-LG3sMY5izpvbbVTdp9zlh_s5X_s9QwcGdf_Nm9o863xtuln_gP9AHzqcME</recordid><startdate>201203</startdate><enddate>201203</enddate><creator>Hajlaoui, F.</creator><creator>Naïli, H.</creator><creator>Yahyaoui, S.</creator><creator>Mhiri, T.</creator><creator>Bataille, T.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201203</creationdate><title>Crystal structures of two enantiomorphous 2-ethylpiperazinediium hexaaquacopper sulfates [(R or S)-C5H14N2][Cu(H2O)6](SO4)2</title><author>Hajlaoui, F. ; Naïli, H. ; Yahyaoui, S. ; Mhiri, T. ; Bataille, T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2037-e1a7c5497801718cfe4dd2482a38d99e2eeb2aa532622e24b5c14b09f3f1f5573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hajlaoui, F.</creatorcontrib><creatorcontrib>Naïli, H.</creatorcontrib><creatorcontrib>Yahyaoui, S.</creatorcontrib><creatorcontrib>Mhiri, T.</creatorcontrib><creatorcontrib>Bataille, T.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hajlaoui, F.</au><au>Naïli, H.</au><au>Yahyaoui, S.</au><au>Mhiri, T.</au><au>Bataille, T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structures of two enantiomorphous 2-ethylpiperazinediium hexaaquacopper sulfates [(R or S)-C5H14N2][Cu(H2O)6](SO4)2</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2012-03</date><risdate>2012</risdate><volume>53</volume><issue>2</issue><spage>334</spage><epage>340</epage><pages>334-340</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>Two new non-centrosymmetric copper sulfates are synthesized under slow evaporation conditions through the use of enantiomorphically pure sources of either (R)-2-methylpiperazine or (S)-2-methylpiperazine. Both crystallize in the non-centrosymmetric
P
2
1
space group, crystal data for [(R)-C
5
H
14
N
2
][Cu(H
2
O)
6
](SO
4
)
2
(
I
),
a
= 6.5276(2) Å,
b
= 11.1955(3) Å,
c
= 12.4559(4) Å, β = 101.196(2)°,
Z
= 2,
V
= 892.95(5) Å
3
and [(S)-C
5
H
14
N
2
][Cu(H
2
O)
6
](SO
4
)
2
(
II
),
a
= 6.5188(2) Å,
b
= 11.1786(2) Å,
c
= 12.4365(3) Å, β = 101.205(1)°,
Z
= 2,
V
= 888.99(4) Å
3
. The three-dimensional structure networks for these compounds consist of isolated [Cu(H
2
O)
6
]
2+
and [(R)-C
5
H
14
N
2
]
2+
or [(S)-C
5
H
14
N
2
]
2+
cations and SO
4
2−
anions linked only by hydrogen bonds. The Cu atom is in a slightly distorted octahedral coordination environment. The crystal packings are influenced by cation-to-anion N-H…O and OW-H…O hydrogen bonds leading to an open framework structures.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0022476612020187</doi><tpages>7</tpages></addata></record> |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Inorganic Chemistry Molecular Optical and Plasma Physics Physical Chemistry Solid State Physics |
| title | Crystal structures of two enantiomorphous 2-ethylpiperazinediium hexaaquacopper sulfates [(R or S)-C5H14N2][Cu(H2O)6](SO4)2 |
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