On some thermodynamic effects in small molecular systems

The behavior of a gas-liquid system in a small volume has been studied. In the absence of the thermodynamic limit, the problem has been examined by methods of statistical physics. This allows the use of new mathematical methods previously applied in nuclear physics. Within the modified droplet model...

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Veröffentlicht in:JETP letters 2014-06, Vol.99 (8), p.452-455
Hauptverfasser: Aslyamov, T. F., Dinariev, O. Yu
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Dinariev, O. Yu
description The behavior of a gas-liquid system in a small volume has been studied. In the absence of the thermodynamic limit, the problem has been examined by methods of statistical physics. This allows the use of new mathematical methods previously applied in nuclear physics. Within the modified droplet model of a real gas sandwiched between two extended plates, an additional component of the pressure, which was previously discussed and exhibits characteristic oscillations at change in the volume, has been found. Qualitative coincidence with the previously reported molecular dynamics simulations has been found.
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subjects Atomic
Biological and Medical Physics
Biophysics
Molecular
Optical and Plasma Physics
Particle and Nuclear Physics
Physics
Physics and Astronomy
Quantum Information Technology
Solid State Physics
Spintronics
title On some thermodynamic effects in small molecular systems
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