EPR study of spin interactions in the poly(3-dodecylthiophene): Fullerene/polyaniline: p-toluenesulfonic acid composite
Magnetic, relaxation, and dynamic parameters of polarons P 1 ·+ , trapped in p -toluenesulfonic aciddoped polyaniline, polarons P 2 ·+ , and fullerene radical anions photoinduced in the poly(3-dodecylthiophene)/methanofullerene composite and in mixtures of these composites have been investigated usi...
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Veröffentlicht in: | High energy chemistry 2016-03, Vol.50 (2), p.127-133 |
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creator | Yudanova, E. I. Bogatyrenko, V. R. Krinichnyi, V. I. |
description | Magnetic, relaxation, and dynamic parameters of polarons P
1
·+
, trapped in
p
-toluenesulfonic aciddoped polyaniline, polarons P
2
·+
, and fullerene radical anions photoinduced in the poly(3-dodecylthiophene)/methanofullerene composite and in mixtures of these composites have been investigated using the EPR technique. It has been shown that spin charge carriers P
2
·+
during diffusion along poly(3-dodecylthiophene) chains interact with P
1
·+
trapped on adjacent polymer chains of polyaniline. The exchange interaction and spin relaxation in the ternary composites is determined by the activated hopping mobility of polarons P
2
·+
and depends on the composition of the material. |
doi_str_mv | 10.1134/S0018143916010112 |
format | Article |
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1
·+
, trapped in
p
-toluenesulfonic aciddoped polyaniline, polarons P
2
·+
, and fullerene radical anions photoinduced in the poly(3-dodecylthiophene)/methanofullerene composite and in mixtures of these composites have been investigated using the EPR technique. It has been shown that spin charge carriers P
2
·+
during diffusion along poly(3-dodecylthiophene) chains interact with P
1
·+
trapped on adjacent polymer chains of polyaniline. The exchange interaction and spin relaxation in the ternary composites is determined by the activated hopping mobility of polarons P
2
·+
and depends on the composition of the material.</description><identifier>ISSN: 0018-1439</identifier><identifier>EISSN: 1608-3148</identifier><identifier>DOI: 10.1134/S0018143916010112</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Nanostructured Systems and Materials ; Physical Chemistry</subject><ispartof>High energy chemistry, 2016-03, Vol.50 (2), p.127-133</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-5aee341c50f5aa30a59728a444eccb62494d3b524d5177a022e8b81e66136d03</citedby><cites>FETCH-LOGICAL-c288t-5aee341c50f5aa30a59728a444eccb62494d3b524d5177a022e8b81e66136d03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0018143916010112$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0018143916010112$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Yudanova, E. I.</creatorcontrib><creatorcontrib>Bogatyrenko, V. R.</creatorcontrib><creatorcontrib>Krinichnyi, V. I.</creatorcontrib><title>EPR study of spin interactions in the poly(3-dodecylthiophene): Fullerene/polyaniline: p-toluenesulfonic acid composite</title><title>High energy chemistry</title><addtitle>High Energy Chem</addtitle><description>Magnetic, relaxation, and dynamic parameters of polarons P
1
·+
, trapped in
p
-toluenesulfonic aciddoped polyaniline, polarons P
2
·+
, and fullerene radical anions photoinduced in the poly(3-dodecylthiophene)/methanofullerene composite and in mixtures of these composites have been investigated using the EPR technique. It has been shown that spin charge carriers P
2
·+
during diffusion along poly(3-dodecylthiophene) chains interact with P
1
·+
trapped on adjacent polymer chains of polyaniline. The exchange interaction and spin relaxation in the ternary composites is determined by the activated hopping mobility of polarons P
2
·+
and depends on the composition of the material.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Nanostructured Systems and Materials</subject><subject>Physical Chemistry</subject><issn>0018-1439</issn><issn>1608-3148</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9UE1LAzEQDaJgrf4AbznqYW0myW7T3qRYFQqK9r6k2VmbkibLJovsv3eXehM8zZt5HwyPkFtgDwBCzj4ZAwVSLKBgwAD4GZkMUGUCpDonk5HORv6SXMV4YIzlTLAJ-X56_6AxdVVPQ01jYz21PmGrTbLBx2GhaY-0Ca6_E1kVKjS9S3sbmj16vF_SdecctgOejRrtrbMel7TJUnDdcI6dq4O3hmpjK2rCsQnRJrwmF7V2EW9-55Rs10_b1Uu2eXt-XT1uMsOVSlmuEYUEk7M611ownS_mXGkpJRqzK7hcyErsci6rHOZzzThHtVOARQGiqJiYEjjFmjbE2GJdNq096rYvgZVjceWf4gYPP3nioPVf2JaH0LV--PIf0w8843EI</recordid><startdate>20160301</startdate><enddate>20160301</enddate><creator>Yudanova, E. I.</creator><creator>Bogatyrenko, V. R.</creator><creator>Krinichnyi, V. I.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160301</creationdate><title>EPR study of spin interactions in the poly(3-dodecylthiophene): Fullerene/polyaniline: p-toluenesulfonic acid composite</title><author>Yudanova, E. I. ; Bogatyrenko, V. R. ; Krinichnyi, V. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-5aee341c50f5aa30a59728a444eccb62494d3b524d5177a022e8b81e66136d03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Nanostructured Systems and Materials</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yudanova, E. I.</creatorcontrib><creatorcontrib>Bogatyrenko, V. R.</creatorcontrib><creatorcontrib>Krinichnyi, V. I.</creatorcontrib><collection>CrossRef</collection><jtitle>High energy chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yudanova, E. I.</au><au>Bogatyrenko, V. R.</au><au>Krinichnyi, V. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>EPR study of spin interactions in the poly(3-dodecylthiophene): Fullerene/polyaniline: p-toluenesulfonic acid composite</atitle><jtitle>High energy chemistry</jtitle><stitle>High Energy Chem</stitle><date>2016-03-01</date><risdate>2016</risdate><volume>50</volume><issue>2</issue><spage>127</spage><epage>133</epage><pages>127-133</pages><issn>0018-1439</issn><eissn>1608-3148</eissn><abstract>Magnetic, relaxation, and dynamic parameters of polarons P
1
·+
, trapped in
p
-toluenesulfonic aciddoped polyaniline, polarons P
2
·+
, and fullerene radical anions photoinduced in the poly(3-dodecylthiophene)/methanofullerene composite and in mixtures of these composites have been investigated using the EPR technique. It has been shown that spin charge carriers P
2
·+
during diffusion along poly(3-dodecylthiophene) chains interact with P
1
·+
trapped on adjacent polymer chains of polyaniline. The exchange interaction and spin relaxation in the ternary composites is determined by the activated hopping mobility of polarons P
2
·+
and depends on the composition of the material.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0018143916010112</doi><tpages>7</tpages></addata></record> |
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subjects | Chemistry Chemistry and Materials Science Nanostructured Systems and Materials Physical Chemistry |
title | EPR study of spin interactions in the poly(3-dodecylthiophene): Fullerene/polyaniline: p-toluenesulfonic acid composite |
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