Specific features of photoconductivity in a polymer composite with a heterometallic Copper(II)/Vanadium(V) complex
The dark conductivity and the photoconductive properties of polymer film composites based on polyvinyl butyral doped with various amounts of the heterometallic complex (H 3 O) 2 (H 2 en)[Cu(en) 2 (H 2 O) 2 ][V 10 O 28 ] · 3H 2 O (where en is ethylenediamine) have been studied. It has been found that...
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| Veröffentlicht in: | High energy chemistry 2012-07, Vol.46 (4), p.229-231 |
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| container_issue | 4 |
| container_start_page | 229 |
| container_title | High energy chemistry |
| container_volume | 46 |
| creator | Davidenko, N. A. Kokozay, V. N. Pavliuk, M. V. Makhankova, V. G. Studzinskii, S. L. Davidenko, I. I. |
| description | The dark conductivity and the photoconductive properties of polymer film composites based on polyvinyl butyral doped with various amounts of the heterometallic complex (H
3
O)
2
(H
2
en)[Cu(en)
2
(H
2
O)
2
][V
10
O
28
] · 3H
2
O (where en is ethylenediamine) have been studied. It has been found that the activation energy of photocurrent in the films increases with an increase in applied electric field strength. An increase in the applied electric field strength has been assumed to result in the release of charge carriers from deeper energy traps that can occur in the heterometallic complex. |
| doi_str_mv | 10.1134/S0018143912040066 |
| format | Article |
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3
O)
2
(H
2
en)[Cu(en)
2
(H
2
O)
2
][V
10
O
28
] · 3H
2
O (where en is ethylenediamine) have been studied. It has been found that the activation energy of photocurrent in the films increases with an increase in applied electric field strength. An increase in the applied electric field strength has been assumed to result in the release of charge carriers from deeper energy traps that can occur in the heterometallic complex.</description><identifier>ISSN: 0018-1439</identifier><identifier>EISSN: 1608-3148</identifier><identifier>DOI: 10.1134/S0018143912040066</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; General Aspects of High Energy Chemistry ; Physical Chemistry</subject><ispartof>High energy chemistry, 2012-07, Vol.46 (4), p.229-231</ispartof><rights>Pleiades Publishing, Ltd. 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-ce06157e43c476227f672190c3553ff4badb015f3043f3448da026c0f2c011ff3</citedby><cites>FETCH-LOGICAL-c288t-ce06157e43c476227f672190c3553ff4badb015f3043f3448da026c0f2c011ff3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0018143912040066$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0018143912040066$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Davidenko, N. A.</creatorcontrib><creatorcontrib>Kokozay, V. N.</creatorcontrib><creatorcontrib>Pavliuk, M. V.</creatorcontrib><creatorcontrib>Makhankova, V. G.</creatorcontrib><creatorcontrib>Studzinskii, S. L.</creatorcontrib><creatorcontrib>Davidenko, I. I.</creatorcontrib><title>Specific features of photoconductivity in a polymer composite with a heterometallic Copper(II)/Vanadium(V) complex</title><title>High energy chemistry</title><addtitle>High Energy Chem</addtitle><description>The dark conductivity and the photoconductive properties of polymer film composites based on polyvinyl butyral doped with various amounts of the heterometallic complex (H
3
O)
2
(H
2
en)[Cu(en)
2
(H
2
O)
2
][V
10
O
28
] · 3H
2
O (where en is ethylenediamine) have been studied. It has been found that the activation energy of photocurrent in the films increases with an increase in applied electric field strength. An increase in the applied electric field strength has been assumed to result in the release of charge carriers from deeper energy traps that can occur in the heterometallic complex.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>General Aspects of High Energy Chemistry</subject><subject>Physical Chemistry</subject><issn>0018-1439</issn><issn>1608-3148</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kDtPwzAUhS0EEqXwA9g8tkPovbbz6IgqHpUqMRS6Rq5jU1dJHNkO0H9PStmQmO7w3e_o6BByi3CHyMVsDYAFCj5HBgIgy87ICDMoEo6iOCejI06O_JJchbAHgBQ4jIhfd1pZYxU1Wsbe60Cdod3ORadcW_Uq2g8bD9S2VNLO1YdGe6pc07lgo6afNu4GsNNRe9foKOt6iFq4rtN-slxOZxvZysr2zWQz_dFq_XVNLoysg775vWPy9vjwunhOVi9Py8X9KlGsKGKiNGSY5lpwJfKMsdxkOcM5KJ6m3BixldUWMDUcBDdciKKSwDIFhilANIaPCZ5ylXcheG3KzttG-kOJUB5HK_-MNjjs5ITht33Xvty73rdDzX-kbwIebyE</recordid><startdate>20120701</startdate><enddate>20120701</enddate><creator>Davidenko, N. A.</creator><creator>Kokozay, V. N.</creator><creator>Pavliuk, M. V.</creator><creator>Makhankova, V. G.</creator><creator>Studzinskii, S. L.</creator><creator>Davidenko, I. I.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20120701</creationdate><title>Specific features of photoconductivity in a polymer composite with a heterometallic Copper(II)/Vanadium(V) complex</title><author>Davidenko, N. A. ; Kokozay, V. N. ; Pavliuk, M. V. ; Makhankova, V. G. ; Studzinskii, S. L. ; Davidenko, I. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-ce06157e43c476227f672190c3553ff4badb015f3043f3448da026c0f2c011ff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>General Aspects of High Energy Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Davidenko, N. A.</creatorcontrib><creatorcontrib>Kokozay, V. N.</creatorcontrib><creatorcontrib>Pavliuk, M. V.</creatorcontrib><creatorcontrib>Makhankova, V. G.</creatorcontrib><creatorcontrib>Studzinskii, S. L.</creatorcontrib><creatorcontrib>Davidenko, I. I.</creatorcontrib><collection>CrossRef</collection><jtitle>High energy chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Davidenko, N. A.</au><au>Kokozay, V. N.</au><au>Pavliuk, M. V.</au><au>Makhankova, V. G.</au><au>Studzinskii, S. L.</au><au>Davidenko, I. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Specific features of photoconductivity in a polymer composite with a heterometallic Copper(II)/Vanadium(V) complex</atitle><jtitle>High energy chemistry</jtitle><stitle>High Energy Chem</stitle><date>2012-07-01</date><risdate>2012</risdate><volume>46</volume><issue>4</issue><spage>229</spage><epage>231</epage><pages>229-231</pages><issn>0018-1439</issn><eissn>1608-3148</eissn><abstract>The dark conductivity and the photoconductive properties of polymer film composites based on polyvinyl butyral doped with various amounts of the heterometallic complex (H
3
O)
2
(H
2
en)[Cu(en)
2
(H
2
O)
2
][V
10
O
28
] · 3H
2
O (where en is ethylenediamine) have been studied. It has been found that the activation energy of photocurrent in the films increases with an increase in applied electric field strength. An increase in the applied electric field strength has been assumed to result in the release of charge carriers from deeper energy traps that can occur in the heterometallic complex.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0018143912040066</doi><tpages>3</tpages></addata></record> |
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| ispartof | High energy chemistry, 2012-07, Vol.46 (4), p.229-231 |
| issn | 0018-1439 1608-3148 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S0018143912040066 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science General Aspects of High Energy Chemistry Physical Chemistry |
| title | Specific features of photoconductivity in a polymer composite with a heterometallic Copper(II)/Vanadium(V) complex |
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