Competitive growth of Al 2 O 3 / YAG /ZrO 2 eutectic ceramics during directional solidification: Effect of interfacial energy

The microstructure evolution and growth behavior of the Al 2 O 3 /Y 3 Al 5 O 12 ( YAG )/ZrO 2 ternary eutectic ceramics during directional solidification were well investigated. During directional solidification of the Al 2 O 3 / YAG /ZrO 2 ternary eutectic ceramics, { } Al 2 O 3 paralleled with {00...

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Veröffentlicht in:Journal of the American Ceramic Society 2019-04, Vol.102 (4), p.2176-2186
Hauptverfasser: Wang, Xu, Zhong, Yujie, Sun, Qian, Qi, Dongqing, Yan, Fuxue, Xian, Quangang, Wang, Dong, Du, Kui, Wang, Jingyang
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container_issue 4
container_start_page 2176
container_title Journal of the American Ceramic Society
container_volume 102
creator Wang, Xu
Zhong, Yujie
Sun, Qian
Qi, Dongqing
Yan, Fuxue
Xian, Quangang
Wang, Dong
Du, Kui
Wang, Jingyang
description The microstructure evolution and growth behavior of the Al 2 O 3 /Y 3 Al 5 O 12 ( YAG )/ZrO 2 ternary eutectic ceramics during directional solidification were well investigated. During directional solidification of the Al 2 O 3 / YAG /ZrO 2 ternary eutectic ceramics, { } Al 2 O 3 paralleled with {001}ZrO 2 while they did not parallel with {001} YAG at the same time in the competitive growth stage. All of the interfaces parallel to each other finally. The area percentage of the Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are 40.4 ± 0.2% and 30.8 ± 0.1%, respectively, higher than that of the Al 2 O 3 / YAG (28.8 ± 0.2%). The content of Al 2 O 3 and YAG phases are 39.9% and 41.1%, respectively, almost double of that of ZrO 2 . The interfaces of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 are shorter and more dispersed than that of the Al 2 O 3 / YAG . It was found that the interfacial energy of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are lower than that of Al 2 O 3 / YAG . It can be concluded that interfacial energy plays a decisive role in affecting the crystallographic orientation and interfaces distribution in the Al 2 O 3 / YAG /ZrO 2 eutectic since the interfaces of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 with lower interfacial energy can be formed more easily during directional solidification. Therefore, the contents of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are higher. This study can provide theoretical guidance for interface design of multi‐phase materials.
doi_str_mv 10.1111/jace.16057
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During directional solidification of the Al 2 O 3 / YAG /ZrO 2 ternary eutectic ceramics, { } Al 2 O 3 paralleled with {001}ZrO 2 while they did not parallel with {001} YAG at the same time in the competitive growth stage. All of the interfaces parallel to each other finally. The area percentage of the Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are 40.4 ± 0.2% and 30.8 ± 0.1%, respectively, higher than that of the Al 2 O 3 / YAG (28.8 ± 0.2%). The content of Al 2 O 3 and YAG phases are 39.9% and 41.1%, respectively, almost double of that of ZrO 2 . The interfaces of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 are shorter and more dispersed than that of the Al 2 O 3 / YAG . It was found that the interfacial energy of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are lower than that of Al 2 O 3 / YAG . It can be concluded that interfacial energy plays a decisive role in affecting the crystallographic orientation and interfaces distribution in the Al 2 O 3 / YAG /ZrO 2 eutectic since the interfaces of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 with lower interfacial energy can be formed more easily during directional solidification. Therefore, the contents of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are higher. This study can provide theoretical guidance for interface design of multi‐phase materials.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/jace.16057</identifier><language>eng</language><ispartof>Journal of the American Ceramic Society, 2019-04, Vol.102 (4), p.2176-2186</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c767-95f6555415f0142378d055f8d53b042dc5417d576708700271ea9da3577bd0bc3</citedby><cites>FETCH-LOGICAL-c767-95f6555415f0142378d055f8d53b042dc5417d576708700271ea9da3577bd0bc3</cites><orcidid>0000-0002-4748-8512 ; 0000-0001-9935-5984</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wang, Xu</creatorcontrib><creatorcontrib>Zhong, Yujie</creatorcontrib><creatorcontrib>Sun, Qian</creatorcontrib><creatorcontrib>Qi, Dongqing</creatorcontrib><creatorcontrib>Yan, Fuxue</creatorcontrib><creatorcontrib>Xian, Quangang</creatorcontrib><creatorcontrib>Wang, Dong</creatorcontrib><creatorcontrib>Du, Kui</creatorcontrib><creatorcontrib>Wang, Jingyang</creatorcontrib><title>Competitive growth of Al 2 O 3 / YAG /ZrO 2 eutectic ceramics during directional solidification: Effect of interfacial energy</title><title>Journal of the American Ceramic Society</title><description>The microstructure evolution and growth behavior of the Al 2 O 3 /Y 3 Al 5 O 12 ( YAG )/ZrO 2 ternary eutectic ceramics during directional solidification were well investigated. During directional solidification of the Al 2 O 3 / YAG /ZrO 2 ternary eutectic ceramics, { } Al 2 O 3 paralleled with {001}ZrO 2 while they did not parallel with {001} YAG at the same time in the competitive growth stage. All of the interfaces parallel to each other finally. The area percentage of the Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are 40.4 ± 0.2% and 30.8 ± 0.1%, respectively, higher than that of the Al 2 O 3 / YAG (28.8 ± 0.2%). The content of Al 2 O 3 and YAG phases are 39.9% and 41.1%, respectively, almost double of that of ZrO 2 . The interfaces of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 are shorter and more dispersed than that of the Al 2 O 3 / YAG . It was found that the interfacial energy of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are lower than that of Al 2 O 3 / YAG . It can be concluded that interfacial energy plays a decisive role in affecting the crystallographic orientation and interfaces distribution in the Al 2 O 3 / YAG /ZrO 2 eutectic since the interfaces of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 with lower interfacial energy can be formed more easily during directional solidification. Therefore, the contents of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are higher. 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During directional solidification of the Al 2 O 3 / YAG /ZrO 2 ternary eutectic ceramics, { } Al 2 O 3 paralleled with {001}ZrO 2 while they did not parallel with {001} YAG at the same time in the competitive growth stage. All of the interfaces parallel to each other finally. The area percentage of the Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are 40.4 ± 0.2% and 30.8 ± 0.1%, respectively, higher than that of the Al 2 O 3 / YAG (28.8 ± 0.2%). The content of Al 2 O 3 and YAG phases are 39.9% and 41.1%, respectively, almost double of that of ZrO 2 . The interfaces of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 are shorter and more dispersed than that of the Al 2 O 3 / YAG . It was found that the interfacial energy of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are lower than that of Al 2 O 3 / YAG . It can be concluded that interfacial energy plays a decisive role in affecting the crystallographic orientation and interfaces distribution in the Al 2 O 3 / YAG /ZrO 2 eutectic since the interfaces of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 with lower interfacial energy can be formed more easily during directional solidification. Therefore, the contents of Al 2 O 3 /ZrO 2 and YAG /ZrO 2 interfaces are higher. This study can provide theoretical guidance for interface design of multi‐phase materials.</abstract><doi>10.1111/jace.16057</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-4748-8512</orcidid><orcidid>https://orcid.org/0000-0001-9935-5984</orcidid></addata></record>
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title Competitive growth of Al 2 O 3 / YAG /ZrO 2 eutectic ceramics during directional solidification: Effect of interfacial energy
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