Coupled Experimental and Thermodynamic Optimization of the Na 2 O–FeO–Fe 2 O 3 –Al 2 O 3 System: Part 1. Phase Diagram Experiments
As part of the complete thermodynamic modeling of the Na 2 O–FeO–Fe 2 O 3 –Al 2 O 3 system, the Na 2 O–FeO–Fe 2 O 3 –Al 2 O 3 phase diagrams in air (1583 and 1698 K) and at Fe saturation (1573 and 1673 K) were investigated using the quenching method followed by Electron Probe Micro‐Analyzer ( EPMA )...
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| Veröffentlicht in: | Journal of the American Ceramic Society 2016-02, Vol.99 (2), p.705-714 |
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| container_title | Journal of the American Ceramic Society |
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| creator | Moosavi‐Khoonsari, Elmira Hudon, Pierre Jung, In‐Ho |
| description | As part of the complete thermodynamic modeling of the Na
2
O–FeO–Fe
2
O
3
–Al
2
O
3
system, the Na
2
O–FeO–Fe
2
O
3
–Al
2
O
3
phase diagrams in air (1583 and 1698 K) and at Fe saturation (1573 and 1673 K) were investigated using the quenching method followed by Electron Probe Micro‐Analyzer (
EPMA
) and X‐ray Diffraction (
XRD
) phase analysis. General features of the phase diagrams in this system were well revealed for the first time. A complete meta‐oxide solid solution between NaAlO
2
and NaFeO
2
was observed. An extensive solid solution of Na
2
(Al,Fe)
12
O
19
Na‐βˮ‐alumina was found and the existence of a miscibility gap in this solution was confirmed. Several compatibility triangles of three‐phase assemblages were also identified in air and at Fe saturation. |
| doi_str_mv | 10.1111/jace.14020 |
| format | Article |
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2
O–FeO–Fe
2
O
3
–Al
2
O
3
system, the Na
2
O–FeO–Fe
2
O
3
–Al
2
O
3
phase diagrams in air (1583 and 1698 K) and at Fe saturation (1573 and 1673 K) were investigated using the quenching method followed by Electron Probe Micro‐Analyzer (
EPMA
) and X‐ray Diffraction (
XRD
) phase analysis. General features of the phase diagrams in this system were well revealed for the first time. A complete meta‐oxide solid solution between NaAlO
2
and NaFeO
2
was observed. An extensive solid solution of Na
2
(Al,Fe)
12
O
19
Na‐βˮ‐alumina was found and the existence of a miscibility gap in this solution was confirmed. Several compatibility triangles of three‐phase assemblages were also identified in air and at Fe saturation.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/jace.14020</identifier><language>eng</language><ispartof>Journal of the American Ceramic Society, 2016-02, Vol.99 (2), p.705-714</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c760-2d7886b03c7bc9e5b80c8ba058ccdf01da4ebbf07d3597473fb91d50ea9688d73</citedby><cites>FETCH-LOGICAL-c760-2d7886b03c7bc9e5b80c8ba058ccdf01da4ebbf07d3597473fb91d50ea9688d73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><contributor>Vanderah, T.</contributor><creatorcontrib>Moosavi‐Khoonsari, Elmira</creatorcontrib><creatorcontrib>Hudon, Pierre</creatorcontrib><creatorcontrib>Jung, In‐Ho</creatorcontrib><title>Coupled Experimental and Thermodynamic Optimization of the Na 2 O–FeO–Fe 2 O 3 –Al 2 O 3 System: Part 1. Phase Diagram Experiments</title><title>Journal of the American Ceramic Society</title><description>As part of the complete thermodynamic modeling of the Na
2
O–FeO–Fe
2
O
3
–Al
2
O
3
system, the Na
2
O–FeO–Fe
2
O
3
–Al
2
O
3
phase diagrams in air (1583 and 1698 K) and at Fe saturation (1573 and 1673 K) were investigated using the quenching method followed by Electron Probe Micro‐Analyzer (
EPMA
) and X‐ray Diffraction (
XRD
) phase analysis. General features of the phase diagrams in this system were well revealed for the first time. A complete meta‐oxide solid solution between NaAlO
2
and NaFeO
2
was observed. An extensive solid solution of Na
2
(Al,Fe)
12
O
19
Na‐βˮ‐alumina was found and the existence of a miscibility gap in this solution was confirmed. Several compatibility triangles of three‐phase assemblages were also identified in air and at Fe saturation.</description><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkLtOw0AQRVcIJEKg4QumRnKY9WvXdFFIACkikUhvzT5MHPklr5EwFSU9f8iX4JAUTDFzb3Pv6DB2zXHCh7ndkbYTHqKPJ2zEo4h7fsLjUzZCRN8T0sdzduHcbrA8keGIfc3qt6awBubvjW3z0lYdFUCVgc3WtmVt-orKXMOq6fIy_6AuryuoM-i2Fp4JfFj9fH4v7GHvLQQw6Glx1C-962x5B2tqO-ATWG_JWbjP6bWl8l-pu2RnGRXOXh3vmG0W883s0VuuHp5m06WnRYyeb4SUscJAC6UTGymJWirCSGptMuSGQqtUhsIEUSJCEWQq4SZCS0kspRHBmN0cYnVbO9faLG2GB6jtU47pHmG6R5j-IQx-AR0WZe4</recordid><startdate>201602</startdate><enddate>201602</enddate><creator>Moosavi‐Khoonsari, Elmira</creator><creator>Hudon, Pierre</creator><creator>Jung, In‐Ho</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201602</creationdate><title>Coupled Experimental and Thermodynamic Optimization of the Na 2 O–FeO–Fe 2 O 3 –Al 2 O 3 System: Part 1. Phase Diagram Experiments</title><author>Moosavi‐Khoonsari, Elmira ; Hudon, Pierre ; Jung, In‐Ho</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c760-2d7886b03c7bc9e5b80c8ba058ccdf01da4ebbf07d3597473fb91d50ea9688d73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Moosavi‐Khoonsari, Elmira</creatorcontrib><creatorcontrib>Hudon, Pierre</creatorcontrib><creatorcontrib>Jung, In‐Ho</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Moosavi‐Khoonsari, Elmira</au><au>Hudon, Pierre</au><au>Jung, In‐Ho</au><au>Vanderah, T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coupled Experimental and Thermodynamic Optimization of the Na 2 O–FeO–Fe 2 O 3 –Al 2 O 3 System: Part 1. Phase Diagram Experiments</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>2016-02</date><risdate>2016</risdate><volume>99</volume><issue>2</issue><spage>705</spage><epage>714</epage><pages>705-714</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>As part of the complete thermodynamic modeling of the Na
2
O–FeO–Fe
2
O
3
–Al
2
O
3
system, the Na
2
O–FeO–Fe
2
O
3
–Al
2
O
3
phase diagrams in air (1583 and 1698 K) and at Fe saturation (1573 and 1673 K) were investigated using the quenching method followed by Electron Probe Micro‐Analyzer (
EPMA
) and X‐ray Diffraction (
XRD
) phase analysis. General features of the phase diagrams in this system were well revealed for the first time. A complete meta‐oxide solid solution between NaAlO
2
and NaFeO
2
was observed. An extensive solid solution of Na
2
(Al,Fe)
12
O
19
Na‐βˮ‐alumina was found and the existence of a miscibility gap in this solution was confirmed. Several compatibility triangles of three‐phase assemblages were also identified in air and at Fe saturation.</abstract><doi>10.1111/jace.14020</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0002-7820 |
| ispartof | Journal of the American Ceramic Society, 2016-02, Vol.99 (2), p.705-714 |
| issn | 0002-7820 1551-2916 |
| language | eng |
| recordid | cdi_crossref_primary_10_1111_jace_14020 |
| source | Wiley Journals |
| title | Coupled Experimental and Thermodynamic Optimization of the Na 2 O–FeO–Fe 2 O 3 –Al 2 O 3 System: Part 1. Phase Diagram Experiments |
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