The Production of Lead-Tin Yellow at Merovingian Schleitheim (Switzerland)

A Merovingian crucible fragment, with internally adhering yellow glass, and yellow glass beads of the same region and period were investigated by non‐destructive XRF, optical microscopy and SEM‐EDS. Although the microstructure and chemical composition of the yellow pigment (lead–tin yellow type II,...

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Veröffentlicht in:Archaeometry 2003-02, Vol.45 (1), p.33-44
Hauptverfasser: Heck, M., Rehren, Th, Hoffmann, P.
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Rehren, Th
Hoffmann, P.
description A Merovingian crucible fragment, with internally adhering yellow glass, and yellow glass beads of the same region and period were investigated by non‐destructive XRF, optical microscopy and SEM‐EDS. Although the microstructure and chemical composition of the yellow pigment (lead–tin yellow type II, ‘PbSnO3’) are almost identical in both the beads and the crucible, in the latter the pigment occurs in a much higher concentration. However, the glass base in the beads and the crucible is very different, indicating that the beads were not manufactured directly from the crucible. Instead, the crucible most likely served to produce lead–tin yellow, which was subsequently mixed elsewhere with a colourless soda–lime glass to produce yellow glass beads.
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source Wiley Online Library Journals Frontfile Complete
subjects BEAD
CRUCIBLE
GLASS
History of science and technology
MANUFACTURE
MEROVINGIAN
PIGMENT
SWITZERLAND
Technology
Writing
paper
painting
sculpture
title The Production of Lead-Tin Yellow at Merovingian Schleitheim (Switzerland)
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