Preparation of Y123 Thick Films by Fluorine-Free MOD Using a Novel Solution

It has been difficult to prepare Y123 films with a thick ness greater than 400 nm by using a single coating-preflring procedure in metal organic deposition (MOD), since shrinkage of the film causes cracks in the pyrolysis process. In the present study, we developed a novel coating solution for crack...

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Veröffentlicht in:IEEE transactions on applied superconductivity 2011-06, Vol.21 (3), p.2775-2778
Hauptverfasser: Yamaguchi, Iwao, Kondo, Wakichi, Hikata, Takeshi, Kamiya, Kunio, Matsui, Hiroaki, Sohma, Mitsugu, Tsukada, Kenichi, Nakagawa, Yoshihiko, Kumagai, Toshiya, Manabe, Takaaki
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container_title IEEE transactions on applied superconductivity
container_volume 21
creator Yamaguchi, Iwao
Kondo, Wakichi
Hikata, Takeshi
Kamiya, Kunio
Matsui, Hiroaki
Sohma, Mitsugu
Tsukada, Kenichi
Nakagawa, Yoshihiko
Kumagai, Toshiya
Manabe, Takaaki
description It has been difficult to prepare Y123 films with a thick ness greater than 400 nm by using a single coating-preflring procedure in metal organic deposition (MOD), since shrinkage of the film causes cracks in the pyrolysis process. In the present study, we developed a novel coating solution for crack-free films with thicknesses greater than 500 nm. We used a Y-, Ba-, and Cu-acetylacetonate-based solution (metal content: ~2mol metal/L) with various additives for the coating solution. We prepared prefired films on CeO 2 -buffered YSZ (CbYSZ) or CeO 2 -buffered SrTiO 3 (CbSTO) substrates using the single coating-preflring process and this solution. When using some additives, we could obtain crack-free preflred films with thicknesses corresponding to 350-800 nm after crystallization to Y123. These prefired films were heat-treated at high-temperatures, resulted in epitaxial Y123 films. The J c and I c of the film on CbSTO was ~2.3 MA/cm 2 and 143 A/cm, respectively.
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In the present study, we developed a novel coating solution for crack-free films with thicknesses greater than 500 nm. We used a Y-, Ba-, and Cu-acetylacetonate-based solution (metal content: ~2mol metal/L) with various additives for the coating solution. We prepared prefired films on CeO 2 -buffered YSZ (CbYSZ) or CeO 2 -buffered SrTiO 3 (CbSTO) substrates using the single coating-preflring process and this solution. When using some additives, we could obtain crack-free preflred films with thicknesses corresponding to 350-800 nm after crystallization to Y123. These prefired films were heat-treated at high-temperatures, resulted in epitaxial Y123 films. 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subjects Additives
Coating
Coating solution
Coatings
Copper
Cracks
Deposition
Epitaxial growth
epitaxial Y123 film
fluorine-free MOD
Pyrolysis
Shrinkage
Substrates
Superconductivity
Surface morphology
thick film
Thick films
title Preparation of Y123 Thick Films by Fluorine-Free MOD Using a Novel Solution
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