Preparation of Y123 Thick Films by Fluorine-Free MOD Using a Novel Solution
It has been difficult to prepare Y123 films with a thick ness greater than 400 nm by using a single coating-preflring procedure in metal organic deposition (MOD), since shrinkage of the film causes cracks in the pyrolysis process. In the present study, we developed a novel coating solution for crack...
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Veröffentlicht in: | IEEE transactions on applied superconductivity 2011-06, Vol.21 (3), p.2775-2778 |
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creator | Yamaguchi, Iwao Kondo, Wakichi Hikata, Takeshi Kamiya, Kunio Matsui, Hiroaki Sohma, Mitsugu Tsukada, Kenichi Nakagawa, Yoshihiko Kumagai, Toshiya Manabe, Takaaki |
description | It has been difficult to prepare Y123 films with a thick ness greater than 400 nm by using a single coating-preflring procedure in metal organic deposition (MOD), since shrinkage of the film causes cracks in the pyrolysis process. In the present study, we developed a novel coating solution for crack-free films with thicknesses greater than 500 nm. We used a Y-, Ba-, and Cu-acetylacetonate-based solution (metal content: ~2mol metal/L) with various additives for the coating solution. We prepared prefired films on CeO 2 -buffered YSZ (CbYSZ) or CeO 2 -buffered SrTiO 3 (CbSTO) substrates using the single coating-preflring process and this solution. When using some additives, we could obtain crack-free preflred films with thicknesses corresponding to 350-800 nm after crystallization to Y123. These prefired films were heat-treated at high-temperatures, resulted in epitaxial Y123 films. The J c and I c of the film on CbSTO was ~2.3 MA/cm 2 and 143 A/cm, respectively. |
doi_str_mv | 10.1109/TASC.2010.2097572 |
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In the present study, we developed a novel coating solution for crack-free films with thicknesses greater than 500 nm. We used a Y-, Ba-, and Cu-acetylacetonate-based solution (metal content: ~2mol metal/L) with various additives for the coating solution. We prepared prefired films on CeO 2 -buffered YSZ (CbYSZ) or CeO 2 -buffered SrTiO 3 (CbSTO) substrates using the single coating-preflring process and this solution. When using some additives, we could obtain crack-free preflred films with thicknesses corresponding to 350-800 nm after crystallization to Y123. These prefired films were heat-treated at high-temperatures, resulted in epitaxial Y123 films. The J c and I c of the film on CbSTO was ~2.3 MA/cm 2 and 143 A/cm, respectively.</description><identifier>ISSN: 1051-8223</identifier><identifier>EISSN: 1558-2515</identifier><identifier>DOI: 10.1109/TASC.2010.2097572</identifier><identifier>CODEN: ITASE9</identifier><language>eng</language><publisher>New York: IEEE</publisher><subject>Additives ; Coating ; Coating solution ; Coatings ; Copper ; Cracks ; Deposition ; Epitaxial growth ; epitaxial Y123 film ; fluorine-free MOD ; Pyrolysis ; Shrinkage ; Substrates ; Superconductivity ; Surface morphology ; thick film ; Thick films</subject><ispartof>IEEE transactions on applied superconductivity, 2011-06, Vol.21 (3), p.2775-2778</ispartof><rights>Copyright The Institute of Electrical and Electronics Engineers, Inc. (IEEE) Jun 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c391t-af50a7230c9a770839f07df73232cb7d80d6c9f895095a20ce9c40beb08053423</citedby><cites>FETCH-LOGICAL-c391t-af50a7230c9a770839f07df73232cb7d80d6c9f895095a20ce9c40beb08053423</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://ieeexplore.ieee.org/document/5688200$$EHTML$$P50$$Gieee$$H</linktohtml><link.rule.ids>314,780,784,796,27924,27925,54758</link.rule.ids><linktorsrc>$$Uhttps://ieeexplore.ieee.org/document/5688200$$EView_record_in_IEEE$$FView_record_in_$$GIEEE</linktorsrc></links><search><creatorcontrib>Yamaguchi, Iwao</creatorcontrib><creatorcontrib>Kondo, Wakichi</creatorcontrib><creatorcontrib>Hikata, Takeshi</creatorcontrib><creatorcontrib>Kamiya, Kunio</creatorcontrib><creatorcontrib>Matsui, Hiroaki</creatorcontrib><creatorcontrib>Sohma, Mitsugu</creatorcontrib><creatorcontrib>Tsukada, Kenichi</creatorcontrib><creatorcontrib>Nakagawa, Yoshihiko</creatorcontrib><creatorcontrib>Kumagai, Toshiya</creatorcontrib><creatorcontrib>Manabe, Takaaki</creatorcontrib><title>Preparation of Y123 Thick Films by Fluorine-Free MOD Using a Novel Solution</title><title>IEEE transactions on applied superconductivity</title><addtitle>TASC</addtitle><description>It has been difficult to prepare Y123 films with a thick ness greater than 400 nm by using a single coating-preflring procedure in metal organic deposition (MOD), since shrinkage of the film causes cracks in the pyrolysis process. In the present study, we developed a novel coating solution for crack-free films with thicknesses greater than 500 nm. We used a Y-, Ba-, and Cu-acetylacetonate-based solution (metal content: ~2mol metal/L) with various additives for the coating solution. We prepared prefired films on CeO 2 -buffered YSZ (CbYSZ) or CeO 2 -buffered SrTiO 3 (CbSTO) substrates using the single coating-preflring process and this solution. When using some additives, we could obtain crack-free preflred films with thicknesses corresponding to 350-800 nm after crystallization to Y123. These prefired films were heat-treated at high-temperatures, resulted in epitaxial Y123 films. The J c and I c of the film on CbSTO was ~2.3 MA/cm 2 and 143 A/cm, respectively.</description><subject>Additives</subject><subject>Coating</subject><subject>Coating solution</subject><subject>Coatings</subject><subject>Copper</subject><subject>Cracks</subject><subject>Deposition</subject><subject>Epitaxial growth</subject><subject>epitaxial Y123 film</subject><subject>fluorine-free MOD</subject><subject>Pyrolysis</subject><subject>Shrinkage</subject><subject>Substrates</subject><subject>Superconductivity</subject><subject>Surface morphology</subject><subject>thick film</subject><subject>Thick films</subject><issn>1051-8223</issn><issn>1558-2515</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>RIE</sourceid><recordid>eNpdkLFOwzAQhi0EEqXwAIjFYmJJOdtxbI9VIYAoFKntwGS5rgMpaVzsBqlvT6JWDEx3J33_6e5D6JLAgBBQt7PhdDSg0I4UlOCCHqEe4VwmlBN-3PbASSIpZafoLMYVAEllynvo-S24jQlmW_oa-wK_E8rw7LO0Xzgvq3XEix3Oq8aHsnZJHpzDL5M7PI9l_YENfvU_rsJTXzVd_hydFKaK7uJQ-2ie389Gj8l48vA0Go4TyxTZJqbgYARlYJURAiRTBYhlIRhl1C7EUsIys6qQioPihoJ1yqawcAuQwFlKWR_d7Pdugv9uXNzqdRmtqypTO99ETTLRfZcx1aLX_9CVb0LdXqcV4VmmOGctRPaQDT7G4Aq9CeXahJ0moDu7urOrO7v6YLfNXO0zpXPuj-eZlBSA_QJ0SXKC</recordid><startdate>201106</startdate><enddate>201106</enddate><creator>Yamaguchi, Iwao</creator><creator>Kondo, Wakichi</creator><creator>Hikata, Takeshi</creator><creator>Kamiya, Kunio</creator><creator>Matsui, Hiroaki</creator><creator>Sohma, Mitsugu</creator><creator>Tsukada, Kenichi</creator><creator>Nakagawa, Yoshihiko</creator><creator>Kumagai, Toshiya</creator><creator>Manabe, Takaaki</creator><general>IEEE</general><general>The Institute of Electrical and Electronics Engineers, Inc. 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In the present study, we developed a novel coating solution for crack-free films with thicknesses greater than 500 nm. We used a Y-, Ba-, and Cu-acetylacetonate-based solution (metal content: ~2mol metal/L) with various additives for the coating solution. We prepared prefired films on CeO 2 -buffered YSZ (CbYSZ) or CeO 2 -buffered SrTiO 3 (CbSTO) substrates using the single coating-preflring process and this solution. When using some additives, we could obtain crack-free preflred films with thicknesses corresponding to 350-800 nm after crystallization to Y123. These prefired films were heat-treated at high-temperatures, resulted in epitaxial Y123 films. The J c and I c of the film on CbSTO was ~2.3 MA/cm 2 and 143 A/cm, respectively.</abstract><cop>New York</cop><pub>IEEE</pub><doi>10.1109/TASC.2010.2097572</doi><tpages>4</tpages></addata></record> |
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subjects | Additives Coating Coating solution Coatings Copper Cracks Deposition Epitaxial growth epitaxial Y123 film fluorine-free MOD Pyrolysis Shrinkage Substrates Superconductivity Surface morphology thick film Thick films |
title | Preparation of Y123 Thick Films by Fluorine-Free MOD Using a Novel Solution |
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