Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes
Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to...
Gespeichert in:
Veröffentlicht in: | IEEE sensors journal 2012-06, Vol.12 (6), p.2091-2099 |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext bestellen |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 2099 |
---|---|
container_issue | 6 |
container_start_page | 2091 |
container_title | IEEE sensors journal |
container_volume | 12 |
creator | Cranny, A. Harris, N. R. Mengyan Nie Wharton, J. A. Wood, R. J. K. Stokes, K. R. |
description | Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to metallic copper is shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion (Cu + ) is complexed by chloride to form the dichlorocuprous anion CuCl 2 - . By comparison, the complexation step during the oxidation of copper to Cu 2+ can involve a number of different chlorocopper(I) complexes of the general form [CuCl (n+1) ] n- depending on the chloride concentration, which can make detection via a stripping reaction difficult. |
doi_str_mv | 10.1109/JSEN.2012.2183867 |
format | Article |
fullrecord | <record><control><sourceid>proquest_RIE</sourceid><recordid>TN_cdi_crossref_primary_10_1109_JSEN_2012_2183867</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><ieee_id>6130569</ieee_id><sourcerecordid>1022909769</sourcerecordid><originalsourceid>FETCH-LOGICAL-c369t-f304f2b4d5bf8974fe3554d033b5a71209640a678f4813378c21635d751bcf5f3</originalsourceid><addsrcrecordid>eNpd0UtLAzEQB_BFFKzVDyBeAiJ42ZrnZteb1PqiaqEWvC37mGjKNlmT3YPghzdLiwdPmcNvZsL8o-iU4AkhOLt6Ws5eJhQTOqEkZWki96IRESKNieTp_lAzHHMm3w-jI-_XGJNMCjmKfpZgvHUeKevQ1DpnvbYG3UIHVReqa_QMhe8dbMB0yKpg2hYcerTGI20Qm4gLtLS17jdo-tlYp2tAK6_NB1pWDsDEC6dNBzVaNEWnTWCzJox2tgZ_HB2oovFwsnvH0epu9jZ9iOev94_Tm3lcsSTrYsUwV7TktShVmkmugAnBa8xYKQpJKM4SjotEpoqnhDGZVpQkTNRSkLJSQrFxdLmd2zr71YPv8o32FTRNYcD2PieY0gxnMskCPf9H17Z3JvwuKIIZ5QmlQZGtqsK9vAOVt05vCvcdUD7kkQ955EMe-S6P0HO27dEA8OcTwrAIe38BdaWFpA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1010324622</pqid></control><display><type>article</type><title>Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes</title><source>IEEE Electronic Library (IEL)</source><creator>Cranny, A. ; Harris, N. R. ; Mengyan Nie ; Wharton, J. A. ; Wood, R. J. K. ; Stokes, K. R.</creator><creatorcontrib>Cranny, A. ; Harris, N. R. ; Mengyan Nie ; Wharton, J. A. ; Wood, R. J. K. ; Stokes, K. R.</creatorcontrib><description>Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to metallic copper is shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion (Cu + ) is complexed by chloride to form the dichlorocuprous anion CuCl 2 - . By comparison, the complexation step during the oxidation of copper to Cu 2+ can involve a number of different chlorocopper(I) complexes of the general form [CuCl (n+1) ] n- depending on the chloride concentration, which can make detection via a stripping reaction difficult.</description><identifier>ISSN: 1530-437X</identifier><identifier>EISSN: 1558-1748</identifier><identifier>DOI: 10.1109/JSEN.2012.2183867</identifier><identifier>CODEN: ISJEAZ</identifier><language>eng</language><publisher>New York: IEEE</publisher><subject>Chemical sensor ; CHLORIDES ; Copper ; COPPER IONS ; CORROSION ; CORROSION TESTS ; CUPRIC IONS ; Electric potential ; ELECTRODES ; Ions ; MEASUREMENT ; Platinum ; Sensors ; SODIUM CHLORIDE ; thick film</subject><ispartof>IEEE sensors journal, 2012-06, Vol.12 (6), p.2091-2099</ispartof><rights>Copyright The Institute of Electrical and Electronics Engineers, Inc. (IEEE) Jun 2012</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c369t-f304f2b4d5bf8974fe3554d033b5a71209640a678f4813378c21635d751bcf5f3</citedby><cites>FETCH-LOGICAL-c369t-f304f2b4d5bf8974fe3554d033b5a71209640a678f4813378c21635d751bcf5f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://ieeexplore.ieee.org/document/6130569$$EHTML$$P50$$Gieee$$H</linktohtml><link.rule.ids>315,782,786,798,27931,27932,54765</link.rule.ids><linktorsrc>$$Uhttps://ieeexplore.ieee.org/document/6130569$$EView_record_in_IEEE$$FView_record_in_$$GIEEE</linktorsrc></links><search><creatorcontrib>Cranny, A.</creatorcontrib><creatorcontrib>Harris, N. R.</creatorcontrib><creatorcontrib>Mengyan Nie</creatorcontrib><creatorcontrib>Wharton, J. A.</creatorcontrib><creatorcontrib>Wood, R. J. K.</creatorcontrib><creatorcontrib>Stokes, K. R.</creatorcontrib><title>Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes</title><title>IEEE sensors journal</title><addtitle>JSEN</addtitle><description>Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to metallic copper is shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion (Cu + ) is complexed by chloride to form the dichlorocuprous anion CuCl 2 - . By comparison, the complexation step during the oxidation of copper to Cu 2+ can involve a number of different chlorocopper(I) complexes of the general form [CuCl (n+1) ] n- depending on the chloride concentration, which can make detection via a stripping reaction difficult.</description><subject>Chemical sensor</subject><subject>CHLORIDES</subject><subject>Copper</subject><subject>COPPER IONS</subject><subject>CORROSION</subject><subject>CORROSION TESTS</subject><subject>CUPRIC IONS</subject><subject>Electric potential</subject><subject>ELECTRODES</subject><subject>Ions</subject><subject>MEASUREMENT</subject><subject>Platinum</subject><subject>Sensors</subject><subject>SODIUM CHLORIDE</subject><subject>thick film</subject><issn>1530-437X</issn><issn>1558-1748</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>RIE</sourceid><recordid>eNpd0UtLAzEQB_BFFKzVDyBeAiJ42ZrnZteb1PqiaqEWvC37mGjKNlmT3YPghzdLiwdPmcNvZsL8o-iU4AkhOLt6Ws5eJhQTOqEkZWki96IRESKNieTp_lAzHHMm3w-jI-_XGJNMCjmKfpZgvHUeKevQ1DpnvbYG3UIHVReqa_QMhe8dbMB0yKpg2hYcerTGI20Qm4gLtLS17jdo-tlYp2tAK6_NB1pWDsDEC6dNBzVaNEWnTWCzJox2tgZ_HB2oovFwsnvH0epu9jZ9iOev94_Tm3lcsSTrYsUwV7TktShVmkmugAnBa8xYKQpJKM4SjotEpoqnhDGZVpQkTNRSkLJSQrFxdLmd2zr71YPv8o32FTRNYcD2PieY0gxnMskCPf9H17Z3JvwuKIIZ5QmlQZGtqsK9vAOVt05vCvcdUD7kkQ955EMe-S6P0HO27dEA8OcTwrAIe38BdaWFpA</recordid><startdate>20120601</startdate><enddate>20120601</enddate><creator>Cranny, A.</creator><creator>Harris, N. R.</creator><creator>Mengyan Nie</creator><creator>Wharton, J. A.</creator><creator>Wood, R. J. K.</creator><creator>Stokes, K. R.</creator><general>IEEE</general><general>The Institute of Electrical and Electronics Engineers, Inc. (IEEE)</general><scope>97E</scope><scope>RIA</scope><scope>RIE</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>7SE</scope><scope>F28</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope></search><sort><creationdate>20120601</creationdate><title>Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes</title><author>Cranny, A. ; Harris, N. R. ; Mengyan Nie ; Wharton, J. A. ; Wood, R. J. K. ; Stokes, K. R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c369t-f304f2b4d5bf8974fe3554d033b5a71209640a678f4813378c21635d751bcf5f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Chemical sensor</topic><topic>CHLORIDES</topic><topic>Copper</topic><topic>COPPER IONS</topic><topic>CORROSION</topic><topic>CORROSION TESTS</topic><topic>CUPRIC IONS</topic><topic>Electric potential</topic><topic>ELECTRODES</topic><topic>Ions</topic><topic>MEASUREMENT</topic><topic>Platinum</topic><topic>Sensors</topic><topic>SODIUM CHLORIDE</topic><topic>thick film</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cranny, A.</creatorcontrib><creatorcontrib>Harris, N. R.</creatorcontrib><creatorcontrib>Mengyan Nie</creatorcontrib><creatorcontrib>Wharton, J. A.</creatorcontrib><creatorcontrib>Wood, R. J. K.</creatorcontrib><creatorcontrib>Stokes, K. R.</creatorcontrib><collection>IEEE All-Society Periodicals Package (ASPP) 2005-present</collection><collection>IEEE All-Society Periodicals Package (ASPP) 1998-Present</collection><collection>IEEE Electronic Library (IEL)</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Corrosion Abstracts</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><jtitle>IEEE sensors journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Cranny, A.</au><au>Harris, N. R.</au><au>Mengyan Nie</au><au>Wharton, J. A.</au><au>Wood, R. J. K.</au><au>Stokes, K. R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes</atitle><jtitle>IEEE sensors journal</jtitle><stitle>JSEN</stitle><date>2012-06-01</date><risdate>2012</risdate><volume>12</volume><issue>6</issue><spage>2091</spage><epage>2099</epage><pages>2091-2099</pages><issn>1530-437X</issn><eissn>1558-1748</eissn><coden>ISJEAZ</coden><abstract>Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to metallic copper is shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion (Cu + ) is complexed by chloride to form the dichlorocuprous anion CuCl 2 - . By comparison, the complexation step during the oxidation of copper to Cu 2+ can involve a number of different chlorocopper(I) complexes of the general form [CuCl (n+1) ] n- depending on the chloride concentration, which can make detection via a stripping reaction difficult.</abstract><cop>New York</cop><pub>IEEE</pub><doi>10.1109/JSEN.2012.2183867</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
fulltext | fulltext_linktorsrc |
identifier | ISSN: 1530-437X |
ispartof | IEEE sensors journal, 2012-06, Vol.12 (6), p.2091-2099 |
issn | 1530-437X 1558-1748 |
language | eng |
recordid | cdi_crossref_primary_10_1109_JSEN_2012_2183867 |
source | IEEE Electronic Library (IEL) |
subjects | Chemical sensor CHLORIDES Copper COPPER IONS CORROSION CORROSION TESTS CUPRIC IONS Electric potential ELECTRODES Ions MEASUREMENT Platinum Sensors SODIUM CHLORIDE thick film |
title | Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-07T04%3A16%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_RIE&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Sensors%20for%20Corrosion%20Detection:%20Measurement%20of%20Copper%20Ions%20in%203.5%25%20Sodium%20Chloride%20Using%20Screen-Printed%20Platinum%20Electrodes&rft.jtitle=IEEE%20sensors%20journal&rft.au=Cranny,%20A.&rft.date=2012-06-01&rft.volume=12&rft.issue=6&rft.spage=2091&rft.epage=2099&rft.pages=2091-2099&rft.issn=1530-437X&rft.eissn=1558-1748&rft.coden=ISJEAZ&rft_id=info:doi/10.1109/JSEN.2012.2183867&rft_dat=%3Cproquest_RIE%3E1022909769%3C/proquest_RIE%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1010324622&rft_id=info:pmid/&rft_ieee_id=6130569&rfr_iscdi=true |