Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes

Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to...

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Veröffentlicht in:IEEE sensors journal 2012-06, Vol.12 (6), p.2091-2099
Hauptverfasser: Cranny, A., Harris, N. R., Mengyan Nie, Wharton, J. A., Wood, R. J. K., Stokes, K. R.
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container_end_page 2099
container_issue 6
container_start_page 2091
container_title IEEE sensors journal
container_volume 12
creator Cranny, A.
Harris, N. R.
Mengyan Nie
Wharton, J. A.
Wood, R. J. K.
Stokes, K. R.
description Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to metallic copper is shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion (Cu + ) is complexed by chloride to form the dichlorocuprous anion CuCl 2 - . By comparison, the complexation step during the oxidation of copper to Cu 2+ can involve a number of different chlorocopper(I) complexes of the general form [CuCl (n+1) ] n- depending on the chloride concentration, which can make detection via a stripping reaction difficult.
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source IEEE Electronic Library (IEL)
subjects Chemical sensor
CHLORIDES
Copper
COPPER IONS
CORROSION
CORROSION TESTS
CUPRIC IONS
Electric potential
ELECTRODES
Ions
MEASUREMENT
Platinum
Sensors
SODIUM CHLORIDE
thick film
title Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes
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