Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes
Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to...
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| Veröffentlicht in: | IEEE sensors journal 2012-06, Vol.12 (6), p.2091-2099 |
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| creator | Cranny, A. Harris, N. R. Mengyan Nie Wharton, J. A. Wood, R. J. K. Stokes, K. R. |
| description | Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to metallic copper is shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion (Cu + ) is complexed by chloride to form the dichlorocuprous anion CuCl 2 - . By comparison, the complexation step during the oxidation of copper to Cu 2+ can involve a number of different chlorocopper(I) complexes of the general form [CuCl (n+1) ] n- depending on the chloride concentration, which can make detection via a stripping reaction difficult. |
| doi_str_mv | 10.1109/JSEN.2012.2183867 |
| format | Article |
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R. ; Mengyan Nie ; Wharton, J. A. ; Wood, R. J. K. ; Stokes, K. R.</creator><creatorcontrib>Cranny, A. ; Harris, N. R. ; Mengyan Nie ; Wharton, J. A. ; Wood, R. J. K. ; Stokes, K. R.</creatorcontrib><description>Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to metallic copper is shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion (Cu + ) is complexed by chloride to form the dichlorocuprous anion CuCl 2 - . 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(IEEE) Jun 2012</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c369t-f304f2b4d5bf8974fe3554d033b5a71209640a678f4813378c21635d751bcf5f3</citedby><cites>FETCH-LOGICAL-c369t-f304f2b4d5bf8974fe3554d033b5a71209640a678f4813378c21635d751bcf5f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://ieeexplore.ieee.org/document/6130569$$EHTML$$P50$$Gieee$$H</linktohtml><link.rule.ids>315,782,786,798,27931,27932,54765</link.rule.ids><linktorsrc>$$Uhttps://ieeexplore.ieee.org/document/6130569$$EView_record_in_IEEE$$FView_record_in_$$GIEEE</linktorsrc></links><search><creatorcontrib>Cranny, A.</creatorcontrib><creatorcontrib>Harris, N. R.</creatorcontrib><creatorcontrib>Mengyan Nie</creatorcontrib><creatorcontrib>Wharton, J. A.</creatorcontrib><creatorcontrib>Wood, R. J. K.</creatorcontrib><creatorcontrib>Stokes, K. R.</creatorcontrib><title>Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes</title><title>IEEE sensors journal</title><addtitle>JSEN</addtitle><description>Planar screen-printed platinum electrodes developed for use in corrosion monitoring have been evaluated using cyclic differential pulse voltammetry and shown to detect cupric ions (Cu 2+ ) over a range up to 100 mM in a background of 3.5% by weight sodium chloride solution. The reduction of Cu 2+ to metallic copper is shown to proceed as two successive single-electron transfer reactions involving an intermediate chemical step where the cuprous ion (Cu + ) is complexed by chloride to form the dichlorocuprous anion CuCl 2 - . By comparison, the complexation step during the oxidation of copper to Cu 2+ can involve a number of different chlorocopper(I) complexes of the general form [CuCl (n+1) ] n- depending on the chloride concentration, which can make detection via a stripping reaction difficult.</description><subject>Chemical sensor</subject><subject>CHLORIDES</subject><subject>Copper</subject><subject>COPPER IONS</subject><subject>CORROSION</subject><subject>CORROSION TESTS</subject><subject>CUPRIC IONS</subject><subject>Electric potential</subject><subject>ELECTRODES</subject><subject>Ions</subject><subject>MEASUREMENT</subject><subject>Platinum</subject><subject>Sensors</subject><subject>SODIUM CHLORIDE</subject><subject>thick film</subject><issn>1530-437X</issn><issn>1558-1748</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>RIE</sourceid><recordid>eNpd0UtLAzEQB_BFFKzVDyBeAiJ42ZrnZteb1PqiaqEWvC37mGjKNlmT3YPghzdLiwdPmcNvZsL8o-iU4AkhOLt6Ws5eJhQTOqEkZWki96IRESKNieTp_lAzHHMm3w-jI-_XGJNMCjmKfpZgvHUeKevQ1DpnvbYG3UIHVReqa_QMhe8dbMB0yKpg2hYcerTGI20Qm4gLtLS17jdo-tlYp2tAK6_NB1pWDsDEC6dNBzVaNEWnTWCzJox2tgZ_HB2oovFwsnvH0epu9jZ9iOev94_Tm3lcsSTrYsUwV7TktShVmkmugAnBa8xYKQpJKM4SjotEpoqnhDGZVpQkTNRSkLJSQrFxdLmd2zr71YPv8o32FTRNYcD2PieY0gxnMskCPf9H17Z3JvwuKIIZ5QmlQZGtqsK9vAOVt05vCvcdUD7kkQ955EMe-S6P0HO27dEA8OcTwrAIe38BdaWFpA</recordid><startdate>20120601</startdate><enddate>20120601</enddate><creator>Cranny, A.</creator><creator>Harris, N. 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| subjects | Chemical sensor CHLORIDES Copper COPPER IONS CORROSION CORROSION TESTS CUPRIC IONS Electric potential ELECTRODES Ions MEASUREMENT Platinum Sensors SODIUM CHLORIDE thick film |
| title | Sensors for Corrosion Detection: Measurement of Copper Ions in 3.5% Sodium Chloride Using Screen-Printed Platinum Electrodes |
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