A Potentiometric \hbox Sensor Combined With Composite Metal Oxide and DOP Plasticizer Operative at Low Temperature
A low-temperature lithium ion based potentiometric CO 2 sensor has been developed by adding 10 mol% of SiO 2 , B 2 O 3 , Li 2 O, and Bi 2 O 3 composite metal oxide mixture to (Li 2 -Ba)CO 3 sensing bicarbonate. The sensors added with different mol% of oxides were tested at different operating temper...
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| Veröffentlicht in: | IEEE sensors journal 2008-09, Vol.8 (9), p.1565-1570 |
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| creator | Satyanarayana, L. Whyo Sup Noh Gwang Ho Jin Woon Young Lee Jin Seong Park |
| description | A low-temperature lithium ion based potentiometric CO 2 sensor has been developed by adding 10 mol% of SiO 2 , B 2 O 3 , Li 2 O, and Bi 2 O 3 composite metal oxide mixture to (Li 2 -Ba)CO 3 sensing bicarbonate. The sensors added with different mol% of oxides were tested at different operating temperatures. The sensor with 1:2:1:1 mol% of the SiO 2 :B 2 O 3 :Li 2 O:Bi 2 O 3 composite metal oxide showed a fair Nernstian correlation and obtained n value equal to 2 at 300degC, where n is the number of reaction electrons. A glassy sensing phase resulted that improved response and recovery. The sensor is also found stable against humidity (70% RH) at 300 degC. However, it is further observed that the performance of the sensor deteriorated with increasing Li 2 O or decreasing B 2 O 3 content. The sensor performance could further be improved at lower temperatures with the introduction of dioctyl phthalate (DOP) plasticizer into the sensing electrode. |
| doi_str_mv | 10.1109/JSEN.2008.925241 |
| format | Article |
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The sensors added with different mol% of oxides were tested at different operating temperatures. The sensor with 1:2:1:1 mol% of the SiO 2 :B 2 O 3 :Li 2 O:Bi 2 O 3 composite metal oxide showed a fair Nernstian correlation and obtained n value equal to 2 at 300degC, where n is the number of reaction electrons. A glassy sensing phase resulted that improved response and recovery. The sensor is also found stable against humidity (70% RH) at 300 degC. However, it is further observed that the performance of the sensor deteriorated with increasing Li 2 O or decreasing B 2 O 3 content. The sensor performance could further be improved at lower temperatures with the introduction of dioctyl phthalate (DOP) plasticizer into the sensing electrode.</description><identifier>ISSN: 1530-437X</identifier><identifier>EISSN: 1558-1748</identifier><identifier>DOI: 10.1109/JSEN.2008.925241</identifier><identifier>CODEN: ISJEAZ</identifier><language>eng</language><publisher>IEEE</publisher><subject>Additives ; Agriculture ; Chemical technology ; Composite metal oxide ; dioctyl phthalate (DOP) plasticizer ; Electrodes ; Electrons ; glassy phase ; Humidity ; Lithium ; low temperature ; Polymers ; potentiometric {\rm CO}_2 sensor ; Temperature sensors ; Testing</subject><ispartof>IEEE sensors journal, 2008-09, Vol.8 (9), p.1565-1570</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1088-dee8436f0e1dbecb450425c0956b729caf6dd16c81817adef70ce80b020344373</citedby><cites>FETCH-LOGICAL-c1088-dee8436f0e1dbecb450425c0956b729caf6dd16c81817adef70ce80b020344373</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://ieeexplore.ieee.org/document/4608838$$EHTML$$P50$$Gieee$$H</linktohtml><link.rule.ids>314,776,780,792,27901,27902,54733</link.rule.ids><linktorsrc>$$Uhttps://ieeexplore.ieee.org/document/4608838$$EView_record_in_IEEE$$FView_record_in_$$GIEEE</linktorsrc></links><search><creatorcontrib>Satyanarayana, L.</creatorcontrib><creatorcontrib>Whyo Sup Noh</creatorcontrib><creatorcontrib>Gwang Ho Jin</creatorcontrib><creatorcontrib>Woon Young Lee</creatorcontrib><creatorcontrib>Jin Seong Park</creatorcontrib><title>A Potentiometric \hbox Sensor Combined With Composite Metal Oxide and DOP Plasticizer Operative at Low Temperature</title><title>IEEE sensors journal</title><addtitle>JSEN</addtitle><description>A low-temperature lithium ion based potentiometric CO 2 sensor has been developed by adding 10 mol% of SiO 2 , B 2 O 3 , Li 2 O, and Bi 2 O 3 composite metal oxide mixture to (Li 2 -Ba)CO 3 sensing bicarbonate. The sensors added with different mol% of oxides were tested at different operating temperatures. The sensor with 1:2:1:1 mol% of the SiO 2 :B 2 O 3 :Li 2 O:Bi 2 O 3 composite metal oxide showed a fair Nernstian correlation and obtained n value equal to 2 at 300degC, where n is the number of reaction electrons. A glassy sensing phase resulted that improved response and recovery. The sensor is also found stable against humidity (70% RH) at 300 degC. However, it is further observed that the performance of the sensor deteriorated with increasing Li 2 O or decreasing B 2 O 3 content. The sensor performance could further be improved at lower temperatures with the introduction of dioctyl phthalate (DOP) plasticizer into the sensing electrode.</description><subject>Additives</subject><subject>Agriculture</subject><subject>Chemical technology</subject><subject>Composite metal oxide</subject><subject>dioctyl phthalate (DOP) plasticizer</subject><subject>Electrodes</subject><subject>Electrons</subject><subject>glassy phase</subject><subject>Humidity</subject><subject>Lithium</subject><subject>low temperature</subject><subject>Polymers</subject><subject>potentiometric {\rm CO}_2 sensor</subject><subject>Temperature sensors</subject><subject>Testing</subject><issn>1530-437X</issn><issn>1558-1748</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>RIE</sourceid><recordid>eNo9kF1LwzAUhoMoOKf3gjf5A50nbdqml2POL6YdbKIXQkmTUxZZl5FEnf56Wydenc_35ZyHkHMGI8aguLxfTB9HMYAYFXEac3ZABixNRcRyLg77PIGIJ_nLMTnx_g2AFXmaD4gb07kNuAnGthicUfR1VdsdXeDGW0cntq3NBjV9NmHVV1vrTUD6gEGuabkzGqncaHpVzul8LX0wynyjo-UWnQzmo5sGOrOfdIntb-vd4Sk5auTa49lfHJKn6-lychvNypu7yXgWKQZCRBpR8CRrAJmuUdU8BR6nCoo0q_O4ULLJtGaZEkywXGpsclAooIYYEt59mgwJ7H2Vs947bKqtM610XxWDqmdW9cyqnlm1Z9ZJLvYSg4j_6zzr7klE8gOxfWlq</recordid><startdate>200809</startdate><enddate>200809</enddate><creator>Satyanarayana, L.</creator><creator>Whyo Sup Noh</creator><creator>Gwang Ho Jin</creator><creator>Woon Young Lee</creator><creator>Jin Seong Park</creator><general>IEEE</general><scope>97E</scope><scope>RIA</scope><scope>RIE</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200809</creationdate><title>A Potentiometric \hbox Sensor Combined With Composite Metal Oxide and DOP Plasticizer Operative at Low Temperature</title><author>Satyanarayana, L. ; Whyo Sup Noh ; Gwang Ho Jin ; Woon Young Lee ; Jin Seong Park</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1088-dee8436f0e1dbecb450425c0956b729caf6dd16c81817adef70ce80b020344373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Additives</topic><topic>Agriculture</topic><topic>Chemical technology</topic><topic>Composite metal oxide</topic><topic>dioctyl phthalate (DOP) plasticizer</topic><topic>Electrodes</topic><topic>Electrons</topic><topic>glassy phase</topic><topic>Humidity</topic><topic>Lithium</topic><topic>low temperature</topic><topic>Polymers</topic><topic>potentiometric {\rm CO}_2 sensor</topic><topic>Temperature sensors</topic><topic>Testing</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Satyanarayana, L.</creatorcontrib><creatorcontrib>Whyo Sup Noh</creatorcontrib><creatorcontrib>Gwang Ho Jin</creatorcontrib><creatorcontrib>Woon Young Lee</creatorcontrib><creatorcontrib>Jin Seong Park</creatorcontrib><collection>IEEE All-Society Periodicals Package (ASPP) 2005-present</collection><collection>IEEE All-Society Periodicals Package (ASPP) 1998–Present</collection><collection>IEEE Xplore</collection><collection>CrossRef</collection><jtitle>IEEE sensors journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Satyanarayana, L.</au><au>Whyo Sup Noh</au><au>Gwang Ho Jin</au><au>Woon Young Lee</au><au>Jin Seong Park</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Potentiometric \hbox Sensor Combined With Composite Metal Oxide and DOP Plasticizer Operative at Low Temperature</atitle><jtitle>IEEE sensors journal</jtitle><stitle>JSEN</stitle><date>2008-09</date><risdate>2008</risdate><volume>8</volume><issue>9</issue><spage>1565</spage><epage>1570</epage><pages>1565-1570</pages><issn>1530-437X</issn><eissn>1558-1748</eissn><coden>ISJEAZ</coden><abstract>A low-temperature lithium ion based potentiometric CO 2 sensor has been developed by adding 10 mol% of SiO 2 , B 2 O 3 , Li 2 O, and Bi 2 O 3 composite metal oxide mixture to (Li 2 -Ba)CO 3 sensing bicarbonate. The sensors added with different mol% of oxides were tested at different operating temperatures. The sensor with 1:2:1:1 mol% of the SiO 2 :B 2 O 3 :Li 2 O:Bi 2 O 3 composite metal oxide showed a fair Nernstian correlation and obtained n value equal to 2 at 300degC, where n is the number of reaction electrons. A glassy sensing phase resulted that improved response and recovery. The sensor is also found stable against humidity (70% RH) at 300 degC. However, it is further observed that the performance of the sensor deteriorated with increasing Li 2 O or decreasing B 2 O 3 content. The sensor performance could further be improved at lower temperatures with the introduction of dioctyl phthalate (DOP) plasticizer into the sensing electrode.</abstract><pub>IEEE</pub><doi>10.1109/JSEN.2008.925241</doi><tpages>6</tpages></addata></record> |
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| source | IEEE Xplore |
| subjects | Additives Agriculture Chemical technology Composite metal oxide dioctyl phthalate (DOP) plasticizer Electrodes Electrons glassy phase Humidity Lithium low temperature Polymers potentiometric {\rm CO}_2 sensor Temperature sensors Testing |
| title | A Potentiometric \hbox Sensor Combined With Composite Metal Oxide and DOP Plasticizer Operative at Low Temperature |
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