Two salts of the 6,6-difluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide anion with different cations

Two salts of the 6,6-difluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide anion with different cations

The crystal structures are reported of the 6,6-difluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide (or 9,9-difluoro-10-oxa-9-boraphenanthren-9-ide) anion with two different cations, namely, potassium 6,6-difluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide, K + ·C 12 H 8 BF 2 O − , ( II ), featuring...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2020-12, Vol.76 (12), p.1837-1840
Hauptverfasser: Budanow, Alexandra, Lerner, Hans-Wolfram, Bolte, Michael
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container_title Acta crystallographica. Section E, Crystallographic communications
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Lerner, Hans-Wolfram
Bolte, Michael
description The crystal structures are reported of the 6,6-difluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide (or 9,9-difluoro-10-oxa-9-boraphenanthren-9-ide) anion with two different cations, namely, potassium 6,6-difluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide, K + ·C 12 H 8 BF 2 O − , ( II ), featuring a polymeric structure, and bis(tetraphenylphosphonium) bis(6,6-difluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide) acetonitrile trisolvate, 2C 24 H 20 P + ·2C 12 H 8 BF 2 O − ·3CH 3 CN, ( III ), which is composed of discrete cations, anions and acetonitrile solvent molecules linked by C—H...O, C—H...N and C—H...F hydrogen bonds. There are only minor differences in the geometrical parameters of the anions in these structures.
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title Two salts of the 6,6-difluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide anion with different cations
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