N , N ′-Diethyl- N , N ′-diphenylpyridine-2,6-dicarboxamide

The asymmetric unit of the title compound, C 23 H 23 N 3 O 2 , contains two molecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn- - anti conformation). There are minor conformational differ...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-04, Vol.68 (4), p.o1099-o1100
Hauptverfasser: Klepetářová, Blanka, Makrlík, Emanuel, Babain, Vasily A., Kašička, Václav
Format: Artikel
Sprache:eng
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Zusammenfassung:The asymmetric unit of the title compound, C 23 H 23 N 3 O 2 , contains two molecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn- - anti conformation). There are minor conformational differences between the two molecules, as reflected in the N pyridine —C—C—N amide torsion angles of −44.9 (3) and 136.0 (2)° for one molecule and 43.5 (3) and −131.1 (2)° for the other molecule. However, the two molecules show significant differences in the orientation of an ethyl group, with corresponding C—C—N—C torsion angles of 86.6 (3)° for one molecule and 79.6 (3)° for the other molecule. In the crystal, molecules are linked by weak C—H...O hydrogen bonds, forming a three-dimensional supramolecular network.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812009026