N , N ′-Diethyl- N , N ′-diphenylpyridine-2,6-dicarboxamide
The asymmetric unit of the title compound, C 23 H 23 N 3 O 2 , contains two molecules in both of which, one amide N atom is in a syn position with respect to the pyridine N atom, while the other amide N atom is in an anti position (the syn- - anti conformation). There are minor conformational differ...
Gespeichert in:
Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-04, Vol.68 (4), p.o1099-o1100 |
---|---|
Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | The asymmetric unit of the title compound, C
23
H
23
N
3
O
2
, contains two molecules in both of which, one amide N atom is in a
syn
position with respect to the pyridine N atom, while the other amide N atom is in an
anti
position (the
syn-
-
anti
conformation). There are minor conformational differences between the two molecules, as reflected in the N
pyridine
—C—C—N
amide
torsion angles of −44.9 (3) and 136.0 (2)° for one molecule and 43.5 (3) and −131.1 (2)° for the other molecule. However, the two molecules show significant differences in the orientation of an ethyl group, with corresponding C—C—N—C torsion angles of 86.6 (3)° for one molecule and 79.6 (3)° for the other molecule. In the crystal, molecules are linked by weak C—H...O hydrogen bonds, forming a three-dimensional supramolecular network. |
---|---|
ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536812009026 |