Bromidobis(morpholine‐4‐dithiocarboxylato‐κ2S,S′)antimony(III)

Bromidobis(morpholine‐4‐dithiocarboxylato‐κ2S,S′)antimony(III)

In the title compound, [SbBr(C45H8NOS2)2], both organic ligands bond to Sb in an S,S′‐bidentate mode, although one of the Sb—S bond lengths is much longer than the other three. A bromide ion completes the very distorted trigonal–bipyramidal geometry about the Sb atom.

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-12, Vol.63 (12), p.m3132-m3132
Hauptverfasser: Sun, Yanlong, Li, Yantuan, Cui, Xin, Lang, Xiuting
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container_title Acta crystallographica. Section E, Structure reports online
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creator Sun, Yanlong
Li, Yantuan
Cui, Xin
Lang, Xiuting
description In the title compound, [SbBr(C45H8NOS2)2], both organic ligands bond to Sb in an S,S′‐bidentate mode, although one of the Sb—S bond lengths is much longer than the other three. A bromide ion completes the very distorted trigonal–bipyramidal geometry about the Sb atom.
doi_str_mv 10.1107/S1600536807060382
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title Bromidobis(morpholine‐4‐dithiocarboxylato‐κ2S,S′)antimony(III)
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