μ‐Oxido‐bis{chlorido[tris(2‐pyridylmethyl)amine]iron(III)} bis(hexafluoridophosphate)

μ‐Oxido‐bis{chlorido[tris(2‐pyridylmethyl)amine]iron(III)} bis(hexafluoridophosphate)

The dinuclear FeIII complex in the title compound, [Fe2Cl2O(C18H18N4)2](PF6)2, lies on a center of inversion. The FeIII atom is chelated by a tetradentate tris(2‐pyridylmethyl)amine ligand via four N atoms and further coordinated by one chloride ion and one bridging oxide O atom, giving a distorted...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-11, Vol.63 (11), p.m2722-m2722
Hauptverfasser: Liu, Ying, Dou, Jianmin, Li, Dacheng, Zhang, Xianxi
Format: Artikel
Sprache:eng
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Zusammenfassung:The dinuclear FeIII complex in the title compound, [Fe2Cl2O(C18H18N4)2](PF6)2, lies on a center of inversion. The FeIII atom is chelated by a tetradentate tris(2‐pyridylmethyl)amine ligand via four N atoms and further coordinated by one chloride ion and one bridging oxide O atom, giving a distorted octahedral coordination geometry.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807049665