1‐Acetyl‐5‐(4‐fluorophenyl)‐3‐(4‐methylphenyl)‐2‐pyrazoline
In the title compound, C18H17FN2O, all bond lengths and angles show normal values. The mean plane of pyrazoline ring makes dihedral angles of 83.33 (9) and 17.03 (9)° with the benzene rings; the two benzene rings make a dihedral angle of 76.01 (5)°. The H atoms of both methyl groups are disordered o...
Gespeichert in:
Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-09, Vol.63 (9), p.o3779-o3779 |
---|---|
1. Verfasser: | |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | o3779 |
---|---|
container_issue | 9 |
container_start_page | o3779 |
container_title | Acta crystallographica. Section E, Structure reports online |
container_volume | 63 |
creator | Guo, Huan‐Mei |
description | In the title compound, C18H17FN2O, all bond lengths and angles show normal values. The mean plane of pyrazoline ring makes dihedral angles of 83.33 (9) and 17.03 (9)° with the benzene rings; the two benzene rings make a dihedral angle of 76.01 (5)°. The H atoms of both methyl groups are disordered over two positions by rotation about their C—C σ bonds, with occupancies of 0.52 (3) and 0.48 (3) for the methyl of the tolyl group, and 0.62 (2) and 0.38 (2) for the methyl belonging to the acetyl group. Weak intermolecular C—H...F hydrogen bonds connect molecules into centrosymmetric dimers in the crystal structure. |
doi_str_mv | 10.1107/S1600536807038810 |
format | Article |
fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1107_S1600536807038810</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>AYE2BH2115</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2475-25f6e7d5484ebae45193e335130ce59192c9b07d9fba925e08eb40a3a4c2e95d3</originalsourceid><addsrcrecordid>eNqFUMtOwzAQtBBIlMIH8AdwCOz6kcTHUBWKVMQBOHCKHGejBrlN5RQhc-IT-Ea-BEcFgcSBw-zOzmj2MIwdI5whQnZ-hymAEmkOGYg8R9hho0FKBm33F99nB33_BIBpxnHEbvDj7b2wtAkuEhVxIuNo3HPnu_WCVsGdxlt8G0vaLIL7MXjEOnjz2rl2RYdsrzGup6OvPWYPl9P7ySyZ315dT4p5YrnMVMJVk1JWK5lLqgxJhVqQEAoFWFIaNbe6gqzWTWU0VwQ5VRKMMNJy0qoWY4bbv9Z3fe-pKde-XRofSoRy6KP800fM6G3mpXUU_g-UxeOUX8w4ohKfFSRqiQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>1‐Acetyl‐5‐(4‐fluorophenyl)‐3‐(4‐methylphenyl)‐2‐pyrazoline</title><source>Access via Wiley Online Library</source><source>Free Full-Text Journals in Chemistry</source><creator>Guo, Huan‐Mei</creator><creatorcontrib>Guo, Huan‐Mei</creatorcontrib><description>In the title compound, C18H17FN2O, all bond lengths and angles show normal values. The mean plane of pyrazoline ring makes dihedral angles of 83.33 (9) and 17.03 (9)° with the benzene rings; the two benzene rings make a dihedral angle of 76.01 (5)°. The H atoms of both methyl groups are disordered over two positions by rotation about their C—C σ bonds, with occupancies of 0.52 (3) and 0.48 (3) for the methyl of the tolyl group, and 0.62 (2) and 0.38 (2) for the methyl belonging to the acetyl group. Weak intermolecular C—H...F hydrogen bonds connect molecules into centrosymmetric dimers in the crystal structure.</description><identifier>ISSN: 1600-5368</identifier><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S1600536807038810</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: Blackwell Publishing Ltd</publisher><ispartof>Acta crystallographica. Section E, Structure reports online, 2007-09, Vol.63 (9), p.o3779-o3779</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1107%2FS1600536807038810$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1107%2FS1600536807038810$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Guo, Huan‐Mei</creatorcontrib><title>1‐Acetyl‐5‐(4‐fluorophenyl)‐3‐(4‐methylphenyl)‐2‐pyrazoline</title><title>Acta crystallographica. Section E, Structure reports online</title><description>In the title compound, C18H17FN2O, all bond lengths and angles show normal values. The mean plane of pyrazoline ring makes dihedral angles of 83.33 (9) and 17.03 (9)° with the benzene rings; the two benzene rings make a dihedral angle of 76.01 (5)°. The H atoms of both methyl groups are disordered over two positions by rotation about their C—C σ bonds, with occupancies of 0.52 (3) and 0.48 (3) for the methyl of the tolyl group, and 0.62 (2) and 0.38 (2) for the methyl belonging to the acetyl group. Weak intermolecular C—H...F hydrogen bonds connect molecules into centrosymmetric dimers in the crystal structure.</description><issn>1600-5368</issn><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqFUMtOwzAQtBBIlMIH8AdwCOz6kcTHUBWKVMQBOHCKHGejBrlN5RQhc-IT-Ea-BEcFgcSBw-zOzmj2MIwdI5whQnZ-hymAEmkOGYg8R9hho0FKBm33F99nB33_BIBpxnHEbvDj7b2wtAkuEhVxIuNo3HPnu_WCVsGdxlt8G0vaLIL7MXjEOnjz2rl2RYdsrzGup6OvPWYPl9P7ySyZ315dT4p5YrnMVMJVk1JWK5lLqgxJhVqQEAoFWFIaNbe6gqzWTWU0VwQ5VRKMMNJy0qoWY4bbv9Z3fe-pKde-XRofSoRy6KP800fM6G3mpXUU_g-UxeOUX8w4ohKfFSRqiQ</recordid><startdate>200709</startdate><enddate>200709</enddate><creator>Guo, Huan‐Mei</creator><general>Blackwell Publishing Ltd</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200709</creationdate><title>1‐Acetyl‐5‐(4‐fluorophenyl)‐3‐(4‐methylphenyl)‐2‐pyrazoline</title><author>Guo, Huan‐Mei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2475-25f6e7d5484ebae45193e335130ce59192c9b07d9fba925e08eb40a3a4c2e95d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guo, Huan‐Mei</creatorcontrib><collection>CrossRef</collection><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo, Huan‐Mei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>1‐Acetyl‐5‐(4‐fluorophenyl)‐3‐(4‐methylphenyl)‐2‐pyrazoline</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><date>2007-09</date><risdate>2007</risdate><volume>63</volume><issue>9</issue><spage>o3779</spage><epage>o3779</epage><pages>o3779-o3779</pages><issn>1600-5368</issn><eissn>1600-5368</eissn><abstract>In the title compound, C18H17FN2O, all bond lengths and angles show normal values. The mean plane of pyrazoline ring makes dihedral angles of 83.33 (9) and 17.03 (9)° with the benzene rings; the two benzene rings make a dihedral angle of 76.01 (5)°. The H atoms of both methyl groups are disordered over two positions by rotation about their C—C σ bonds, with occupancies of 0.52 (3) and 0.48 (3) for the methyl of the tolyl group, and 0.62 (2) and 0.38 (2) for the methyl belonging to the acetyl group. Weak intermolecular C—H...F hydrogen bonds connect molecules into centrosymmetric dimers in the crystal structure.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1107/S1600536807038810</doi></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1600-5368 |
ispartof | Acta crystallographica. Section E, Structure reports online, 2007-09, Vol.63 (9), p.o3779-o3779 |
issn | 1600-5368 1600-5368 |
language | eng |
recordid | cdi_crossref_primary_10_1107_S1600536807038810 |
source | Access via Wiley Online Library; Free Full-Text Journals in Chemistry |
title | 1‐Acetyl‐5‐(4‐fluorophenyl)‐3‐(4‐methylphenyl)‐2‐pyrazoline |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T06%3A21%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=1%E2%80%90Acetyl%E2%80%905%E2%80%90(4%E2%80%90fluorophenyl)%E2%80%903%E2%80%90(4%E2%80%90methylphenyl)%E2%80%902%E2%80%90pyrazoline&rft.jtitle=Acta%20crystallographica.%20Section%20E,%20Structure%20reports%20online&rft.au=Guo,%20Huan%E2%80%90Mei&rft.date=2007-09&rft.volume=63&rft.issue=9&rft.spage=o3779&rft.epage=o3779&rft.pages=o3779-o3779&rft.issn=1600-5368&rft.eissn=1600-5368&rft_id=info:doi/10.1107/S1600536807038810&rft_dat=%3Cwiley_cross%3EAYE2BH2115%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |