Bis(1,10‐phenanthroline)(2,2,6,6‐tetramethylheptane‐3,5‐dionato)potassium(I) benzene sesquisolvate

Bis(1,10‐phenanthroline)(2,2,6,6‐tetramethylheptane‐3,5‐dionato)potassium(I) benzene sesquisolvate

The title compound, [K(C11H19O2)(C12H8N2)2]·1.5C6H6, is a potassium heteroligand β‐diketonate complex with a mononuclear molecular structure in which a K+ cation is coordinated by a dipivaloylmethanate anion (2,2,6,6‐tetramethylheptane‐3,5‐dionate, dpm) and two 1,10‐phenanthroline (phen) molecules a...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-08, Vol.63 (8), p.m2195-m2195
Hauptverfasser: Tsymbarenko, Dmitry M., Korsakov, Igor E., Kaul, Andrey R., Kemnitz, Erhard, Troyanov, Sergey I.
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container_issue 8
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container_title Acta crystallographica. Section E, Structure reports online
container_volume 63
creator Tsymbarenko, Dmitry M.
Korsakov, Igor E.
Kaul, Andrey R.
Kemnitz, Erhard
Troyanov, Sergey I.
description The title compound, [K(C11H19O2)(C12H8N2)2]·1.5C6H6, is a potassium heteroligand β‐diketonate complex with a mononuclear molecular structure in which a K+ cation is coordinated by a dipivaloylmethanate anion (2,2,6,6‐tetramethylheptane‐3,5‐dionate, dpm) and two 1,10‐phenanthroline (phen) molecules as bidentate ligands. The coordination number (CN) of K in the K(dpm)(phen)2 molecule is 6 and the coordinating atoms form a distorted trigonal prism. Face‐to‐face stacking interactions between phen ligands of neighbouring molecules [with perpendicular separations of 3.48 (5) Å] cause them to associate into chains along the [001] direction. The benzene solvent molecules in the structural cavities are edge‐to‐face stacked with the phen ligands.
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title Bis(1,10‐phenanthroline)(2,2,6,6‐tetramethylheptane‐3,5‐dionato)potassium(I) benzene sesquisolvate
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