A triazine derivative with a triple‐decker sandwich conformation
In dimethyl 3,3′‐[6‐methoxy‐1,3,5‐triazine‐2,4‐diyl)bis(oxy)]bis(4‐benzyloxy‐5‐methoxybenzoate), C36H33N3O11, a new triazine derivative, the benzyloxy groups adopt an interesting conformation in which they are positioned above and below the triazine ring `core' of the molecule to form an int...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-02, Vol.63 (2), p.o624-o626 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | In dimethyl 3,3′‐[6‐methoxy‐1,3,5‐triazine‐2,4‐diyl)bis(oxy)]bis(4‐benzyloxy‐5‐methoxybenzoate), C36H33N3O11, a new triazine derivative, the benzyloxy groups adopt an interesting conformation in which they are positioned above and below the triazine ring `core' of the molecule to form an intramolecular triple‐decker sandwich. The ester carbonyl O atoms of adjacent molecules in the crystal structure participate in non‐conventional (alkyl)C—H⋯O hydrogen bonds [averaging 2.45 (1)Å] about an inversion centre to give a weakly hydrogen‐bonded dimer. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536806054018 |