Dipotassium aquabis(pyrazine‐2,3‐dicarboxylato‐κ2N,O)cuprate(II) hexahydrate

The crystal structure of the title compound, K2[Cu(C6H2N2O4)2(H2O)]·6H2O, consists of mononuclear [Cu(pzdc)2­(H2O)]2− complex anions (pzdc is pyrazine‐2,3‐di­carboxyl­ate), K+ cations and water mol­ecules, held together by means of K—O/OW bonds and an extended OW—H⋯O/OW and OW—H⋯N hydrogen‐bond netw...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2003-09, Vol.59 (9), p.m800-m802
Hauptverfasser: Castillo, Oscar, Beobide, Garikoitz, Luque, Antonio, Román, Pascual
Format: Artikel
Sprache:eng
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Zusammenfassung:The crystal structure of the title compound, K2[Cu(C6H2N2O4)2(H2O)]·6H2O, consists of mononuclear [Cu(pzdc)2­(H2O)]2− complex anions (pzdc is pyrazine‐2,3‐di­carboxyl­ate), K+ cations and water mol­ecules, held together by means of K—O/OW bonds and an extended OW—H⋯O/OW and OW—H⋯N hydrogen‐bond network. The distorted square‐pyramidal coordination of the Cu atom is achieved by two N and two O donor atoms from two bidentate pzdc ligands in the basal plane, while a water mol­ecule occupies the apical position with a longer metal–O distance.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053680301732X