Dipotassium aquabis(pyrazine‐2,3‐dicarboxylato‐κ2N,O)cuprate(II) hexahydrate
The crystal structure of the title compound, K2[Cu(C6H2N2O4)2(H2O)]·6H2O, consists of mononuclear [Cu(pzdc)2(H2O)]2− complex anions (pzdc is pyrazine‐2,3‐dicarboxylate), K+ cations and water molecules, held together by means of K—O/OW bonds and an extended OW—H⋯O/OW and OW—H⋯N hydrogen‐bond netw...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2003-09, Vol.59 (9), p.m800-m802 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The crystal structure of the title compound, K2[Cu(C6H2N2O4)2(H2O)]·6H2O, consists of mononuclear [Cu(pzdc)2(H2O)]2− complex anions (pzdc is pyrazine‐2,3‐dicarboxylate), K+ cations and water molecules, held together by means of K—O/OW bonds and an extended OW—H⋯O/OW and OW—H⋯N hydrogen‐bond network. The distorted square‐pyramidal coordination of the Cu atom is achieved by two N and two O donor atoms from two bidentate pzdc ligands in the basal plane, while a water molecule occupies the apical position with a longer metal–O distance. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S160053680301732X |