Isotope and Quantum Effects in Vibrational State Distributions of Photodesorbed Ammonia

A marked quantum effect has been observed in the vibrational state distribution of photodesorbed ammonia. Namely, for quantum numbers larger than zero, symmetric and antisymmetric levels in the {nu}{sub 2} mode of the desorbed ammonia molecule are unequally populated. A strong propensity for symmetr...

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Veröffentlicht in:	Physical Review Letters 1997-02, Vol.78 (6), p.1174-1177
Hauptverfasser:	Bornscheuer, K-H., Nessler, W., Binetti, M., Hasselbrink, E., Saalfrank, P.
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY AMMONIA BINDING ENERGY CHEMISORPTION COPPER DESORPTION ISOTOPE EFFECTS PHYSICS POTENTIAL ENERGY QUANTUM NUMBERS VIBRATIONAL STATES
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