Postcollision-interaction effects in HCl following photofragmentation near the chlorine K edge

Ion time-of-flight mass spectroscopy was used to study the relaxation dynamics of HCl following photoexcitation in the vicinity of the Cl K threshold ({approx}2.8 keV). Detailed observations of molecular fragmentation mediated by postcollision interaction between a photoelectron and an Auger electro...

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Veröffentlicht in:Physical Review A 1998-06, Vol.57 (6), p.R4090-R4093
Hauptverfasser: Hansen, D. L., Armen, G. B., Arrasate, M. E., Cotter, J., Fisher, G. R., Leung, K. T., Levin, J. C., Martin, R., Neill, P., Perera, R. C. C., Sellin, I. A., Simon, M., Uehara, Y., Vanderford, B., Whitfield, S. B., Lindle, D. W.
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container_end_page R4093
container_issue 6
container_start_page R4090
container_title Physical Review A
container_volume 57
creator Hansen, D. L.
Armen, G. B.
Arrasate, M. E.
Cotter, J.
Fisher, G. R.
Leung, K. T.
Levin, J. C.
Martin, R.
Neill, P.
Perera, R. C. C.
Sellin, I. A.
Simon, M.
Uehara, Y.
Vanderford, B.
Whitfield, S. B.
Lindle, D. W.
description Ion time-of-flight mass spectroscopy was used to study the relaxation dynamics of HCl following photoexcitation in the vicinity of the Cl K threshold ({approx}2.8 keV). Detailed observations of molecular fragmentation mediated by postcollision interaction between a photoelectron and an Auger electron are presented, evidenced by the recapture of Cl K photoelectrons by either Cl{sup n+} or H{sup +} dissociation fragments. {copyright} {ital 1998} {ital The American Physical Society}
doi_str_mv 10.1103/PhysRevA.57.R4090
format Article
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source American Physical Society Journals
subjects AUGER EFFECT
CHLORINE IONS
DISSOCIATION
EXCITATION
FRAGMENTATION
HYDROCHLORIC ACID
HYDROGEN IONS 1 PLUS
MASS SPECTROSCOPY
PHOTOELECTRON SPECTROSCOPY
PHOTON-MOLECULE COLLISIONS
PHYSICS
RELAXATION
TIME-OF-FLIGHT MASS SPECTROMETERS
title Postcollision-interaction effects in HCl following photofragmentation near the chlorine K edge
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