Organometallic Chemistry can Simplify the Synthesis of Important Biologically Active Natural Products [and Discussion]

The stereoselectivity of the Pauson--Khand reaction used for the construction of a 6a-carboprostaglandin is described, and a mechanistic hypothesis is proposed to explain the experimentally observed results. A further illustration of the stereoselectivity of the dicobaltoctacarbonyl-mediated cycliza...

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Veröffentlicht in:	Philosophical transactions of the Royal Society of London. Series A: Mathematical and physical sciences 1988-11, Vol.326 (1592), p.641-651
Hauptverfasser:	Becker, D., Carter, P., Elliott, J., Lewis, R., Magnus, P. D., Principe, L., Slater, M., Golding, B. T., Holmes, A. B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Alkynes Atoms Biochemistry Chemicals Molecules Nitrogen Organic chemistry Reagents Tetrahedrons
Online-Zugang:	Volltext
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