Flame photometric studies of reactions induced by nitric oxide in hydrogen-oxygen—nitrogen flames

Flame photometric studies of reactions induced by nitric oxide in hydrogen-oxygen—nitrogen flames

It has been found that nitric oxide is an effective homogeneous catalyst for the recombination of atomic hydrogen and hydroxyl radicals in fuel-rich flames of hydrogen, oxygen and nitrogen at atmospheric pressure. The results are consistent with the mechanism H + NO + M ⇌ HNO +M, HNO + H → H2 + NO (...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences Mathematical and physical sciences, 1964-01, Vol.277 (1369), p.143-154
Hauptverfasser: Bulewicz, Elžbieta M., Sugden, Theodore Morris
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 154
container_issue 1369
container_start_page 143
container_title Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences
container_volume 277
creator Bulewicz, Elžbieta M.
Sugden, Theodore Morris
description It has been found that nitric oxide is an effective homogeneous catalyst for the recombination of atomic hydrogen and hydroxyl radicals in fuel-rich flames of hydrogen, oxygen and nitrogen at atmospheric pressure. The results are consistent with the mechanism H + NO + M ⇌ HNO +M, HNO + H → H2 + NO (k4), HNO + HO → H2O + NO or H2 + NO2 (k5), and the following values for k4 and k5 are obtained: k4 = (1·0 ± 0·5) x 10-11cm3 molecule-1 s-1, k5 = (1·5 ±0·5) x 10-10 cm3 molecule-1 s-1, with no significant temperature effect from 1600 to 2000 °K. Alternative mechanisms are discussed.
doi_str_mv 10.1098/rspa.1964.0012
format Article
fullrecord <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1098_rspa_1964_0012</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_V84_KPQHPCLJ_S</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3402-771a6da33de49513d556846348fd5559a955c9f70d989ca75073b440199d9cf03</originalsourceid><addsrcrecordid>eNp9UM1uEzEQtiqQCG2vPfsFNh3H67V9rCLaUiIRWuA6cm1v67ZZR_YGZXviIXhCngRvgiohBKexR9_ffIScMJgy0Oo05bWZMt3UUwA2OyCTGQheadboV2QCoKCqGw5vyNucHwBAC8UnxJ4_mZWn6_vYx5XvU7A09xsXfKaxpckb24fYZRo6t7He0duBdmEHi9vgfNnT-8GleOe7Km6HMn5-_zEixg1tR_F8RF635in749_zkHw5f_d5flktPl68n58tKstrmFVSMtM4w7nztRaMOyEaVSLXqi1PoY0WwupWgtNKWyMFSH5b18C0dtq2wA_JdK9rU8w5-RbXKaxMGpABjhXhWBGOFeFYUSHkPSHFoQSLNvh-wIe4SV354vXN8oxprr7NpAyMNxpBcVZcAQQ-h_VObgRgAWDIeeNxB_vT5m9X_j_Xf2at9qyQe799ucykR2wklwK_qho_LD9dLueLK7zhvwCKZaGD</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Flame photometric studies of reactions induced by nitric oxide in hydrogen-oxygen—nitrogen flames</title><source>JSTOR Mathematics &amp; Statistics</source><source>Jstor Complete Legacy</source><creator>Bulewicz, Elžbieta M. ; Sugden, Theodore Morris</creator><creatorcontrib>Bulewicz, Elžbieta M. ; Sugden, Theodore Morris</creatorcontrib><description>It has been found that nitric oxide is an effective homogeneous catalyst for the recombination of atomic hydrogen and hydroxyl radicals in fuel-rich flames of hydrogen, oxygen and nitrogen at atmospheric pressure. The results are consistent with the mechanism H + NO + M ⇌ HNO +M, HNO + H → H2 + NO (k4), HNO + HO → H2O + NO or H2 + NO2 (k5), and the following values for k4 and k5 are obtained: k4 = (1·0 ± 0·5) x 10-11cm3 molecule-1 s-1, k5 = (1·5 ±0·5) x 10-10 cm3 molecule-1 s-1, with no significant temperature effect from 1600 to 2000 °K. Alternative mechanisms are discussed.</description><identifier>ISSN: 0080-4630</identifier><identifier>EISSN: 2053-9169</identifier><identifier>DOI: 10.1098/rspa.1964.0012</identifier><language>eng</language><publisher>London: The Royal Society</publisher><ispartof>Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences, 1964-01, Vol.277 (1369), p.143-154</ispartof><rights>Scanned images copyright © 2017, Royal Society</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3402-771a6da33de49513d556846348fd5559a955c9f70d989ca75073b440199d9cf03</citedby><cites>FETCH-LOGICAL-c3402-771a6da33de49513d556846348fd5559a955c9f70d989ca75073b440199d9cf03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Bulewicz, Elžbieta M.</creatorcontrib><creatorcontrib>Sugden, Theodore Morris</creatorcontrib><title>Flame photometric studies of reactions induced by nitric oxide in hydrogen-oxygen—nitrogen flames</title><title>Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences</title><addtitle>Proc. R. Soc. Lond. A</addtitle><addtitle>Proc. R. Soc. Lond. A</addtitle><description>It has been found that nitric oxide is an effective homogeneous catalyst for the recombination of atomic hydrogen and hydroxyl radicals in fuel-rich flames of hydrogen, oxygen and nitrogen at atmospheric pressure. The results are consistent with the mechanism H + NO + M ⇌ HNO +M, HNO + H → H2 + NO (k4), HNO + HO → H2O + NO or H2 + NO2 (k5), and the following values for k4 and k5 are obtained: k4 = (1·0 ± 0·5) x 10-11cm3 molecule-1 s-1, k5 = (1·5 ±0·5) x 10-10 cm3 molecule-1 s-1, with no significant temperature effect from 1600 to 2000 °K. Alternative mechanisms are discussed.</description><issn>0080-4630</issn><issn>2053-9169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1964</creationdate><recordtype>article</recordtype><recordid>eNp9UM1uEzEQtiqQCG2vPfsFNh3H67V9rCLaUiIRWuA6cm1v67ZZR_YGZXviIXhCngRvgiohBKexR9_ffIScMJgy0Oo05bWZMt3UUwA2OyCTGQheadboV2QCoKCqGw5vyNucHwBAC8UnxJ4_mZWn6_vYx5XvU7A09xsXfKaxpckb24fYZRo6t7He0duBdmEHi9vgfNnT-8GleOe7Km6HMn5-_zEixg1tR_F8RF635in749_zkHw5f_d5flktPl68n58tKstrmFVSMtM4w7nztRaMOyEaVSLXqi1PoY0WwupWgtNKWyMFSH5b18C0dtq2wA_JdK9rU8w5-RbXKaxMGpABjhXhWBGOFeFYUSHkPSHFoQSLNvh-wIe4SV354vXN8oxprr7NpAyMNxpBcVZcAQQ-h_VObgRgAWDIeeNxB_vT5m9X_j_Xf2at9qyQe799ucykR2wklwK_qho_LD9dLueLK7zhvwCKZaGD</recordid><startdate>19640121</startdate><enddate>19640121</enddate><creator>Bulewicz, Elžbieta M.</creator><creator>Sugden, Theodore Morris</creator><general>The Royal Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19640121</creationdate><title>Flame photometric studies of reactions induced by nitric oxide in hydrogen-oxygen—nitrogen flames</title><author>Bulewicz, Elžbieta M. ; Sugden, Theodore Morris</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3402-771a6da33de49513d556846348fd5559a955c9f70d989ca75073b440199d9cf03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1964</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Bulewicz, Elžbieta M.</creatorcontrib><creatorcontrib>Sugden, Theodore Morris</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bulewicz, Elžbieta M.</au><au>Sugden, Theodore Morris</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Flame photometric studies of reactions induced by nitric oxide in hydrogen-oxygen—nitrogen flames</atitle><jtitle>Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences</jtitle><stitle>Proc. R. Soc. Lond. A</stitle><addtitle>Proc. R. Soc. Lond. A</addtitle><date>1964-01-21</date><risdate>1964</risdate><volume>277</volume><issue>1369</issue><spage>143</spage><epage>154</epage><pages>143-154</pages><issn>0080-4630</issn><eissn>2053-9169</eissn><abstract>It has been found that nitric oxide is an effective homogeneous catalyst for the recombination of atomic hydrogen and hydroxyl radicals in fuel-rich flames of hydrogen, oxygen and nitrogen at atmospheric pressure. The results are consistent with the mechanism H + NO + M ⇌ HNO +M, HNO + H → H2 + NO (k4), HNO + HO → H2O + NO or H2 + NO2 (k5), and the following values for k4 and k5 are obtained: k4 = (1·0 ± 0·5) x 10-11cm3 molecule-1 s-1, k5 = (1·5 ±0·5) x 10-10 cm3 molecule-1 s-1, with no significant temperature effect from 1600 to 2000 °K. Alternative mechanisms are discussed.</abstract><cop>London</cop><pub>The Royal Society</pub><doi>10.1098/rspa.1964.0012</doi><tpages>12</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0080-4630
ispartof Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences, 1964-01, Vol.277 (1369), p.143-154
issn 0080-4630
2053-9169
language eng
recordid cdi_crossref_primary_10_1098_rspa_1964_0012
source JSTOR Mathematics & Statistics; Jstor Complete Legacy
title Flame photometric studies of reactions induced by nitric oxide in hydrogen-oxygen—nitrogen flames
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-18T01%3A44%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Flame%20photometric%20studies%20of%20reactions%20induced%20by%20nitric%20oxide%20in%20hydrogen-oxygen%E2%80%94nitrogen%20flames&rft.jtitle=Proceedings%20of%20the%20Royal%20Society%20of%20London.%20Series%20A,%20Mathematical%20and%20physical%20sciences&rft.au=Bulewicz,%20El%C5%BEbieta%20M.&rft.date=1964-01-21&rft.volume=277&rft.issue=1369&rft.spage=143&rft.epage=154&rft.pages=143-154&rft.issn=0080-4630&rft.eissn=2053-9169&rft_id=info:doi/10.1098/rspa.1964.0012&rft_dat=%3Cistex_cross%3Eark_67375_V84_KPQHPCLJ_S%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true