Synthesis and electrochemical properties of Li5+ x Fe1– x Mn x O4 with an antifluorite-type structure as a lithium battery cathode

Synthesis and electrochemical properties of Li5+ x Fe1– x Mn x O4 with an antifluorite-type structure as a lithium battery cathode

A new antifluorite-structured Li5+xFe1–xMnxO4 was synthesized by conventional solid-state reaction and the lithium (de-)intercalation properties were characterized from electrochemical measurements. A single phase with a Li6MnO4-type structure was obtained for the x ≥ 0.6 compositions. The first dis...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2024-03, Vol.53 (4)
Hauptverfasser: Goto, Ryosuke, Taminato, Sou, Mori, Daisuke, Imanishi, Nobuyuki
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue 4
container_start_page
container_title Chemistry letters
container_volume 53
creator Goto, Ryosuke
Taminato, Sou
Mori, Daisuke
Imanishi, Nobuyuki
description A new antifluorite-structured Li5+xFe1–xMnxO4 was synthesized by conventional solid-state reaction and the lithium (de-)intercalation properties were characterized from electrochemical measurements. A single phase with a Li6MnO4-type structure was obtained for the x ≥ 0.6 compositions. The first discharge capacity of a Li5.6Fe0.4Mn0.6O4 (x = 0.6) electrode treated by ball milling was 450 mAh/g. The reversible reaction continued to proceed with ca. 200 mAh/g after subsequent cycles. A new iron–manganese system with an antifluorite structure could be a potential candidate as a high-capacity cathode material.
doi_str_mv 10.1093/chemle/upae046
format Article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1093_chemle_upae046</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1093_chemle_upae046</sourcerecordid><originalsourceid>FETCH-crossref_primary_10_1093_chemle_upae0463</originalsourceid><addsrcrecordid>eNqVj7FOwzAQhi0EEqGwMt-O0tpJmrYzomKgYoDdct2LYuTE0fkiyMbAG_CGPAmu6Asgnf77h_-_0yfErZJzJTflwrbYeVyMg0FZ1WciU2W1zuVKLc9FJsu6zleyKC7FVYxvUsr1piwy8fUy9dxidBFMfwD0aJnC8ZSzxsNAYUBihxFCA09ueQcfsEX18_mdzK5P8lzBu-M21dOwa_wYyDHmPA0IkWm0PBKCSQ_Ap6AbO9gbZqQJrOE2HPBaXDTGR7w57ZmYbx9e7x9zSyFGwkYP5DpDk1ZSH1n1H6s-sZb_LvwCFSpi4w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis and electrochemical properties of Li5+ x Fe1– x Mn x O4 with an antifluorite-type structure as a lithium battery cathode</title><source>Oxford University Press Journals All Titles (1996-Current)</source><creator>Goto, Ryosuke ; Taminato, Sou ; Mori, Daisuke ; Imanishi, Nobuyuki</creator><creatorcontrib>Goto, Ryosuke ; Taminato, Sou ; Mori, Daisuke ; Imanishi, Nobuyuki</creatorcontrib><description>A new antifluorite-structured Li5+xFe1–xMnxO4 was synthesized by conventional solid-state reaction and the lithium (de-)intercalation properties were characterized from electrochemical measurements. A single phase with a Li6MnO4-type structure was obtained for the x ≥ 0.6 compositions. The first discharge capacity of a Li5.6Fe0.4Mn0.6O4 (x = 0.6) electrode treated by ball milling was 450 mAh/g. The reversible reaction continued to proceed with ca. 200 mAh/g after subsequent cycles. A new iron–manganese system with an antifluorite structure could be a potential candidate as a high-capacity cathode material.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1093/chemle/upae046</identifier><language>eng</language><ispartof>Chemistry letters, 2024-03, Vol.53 (4)</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-crossref_primary_10_1093_chemle_upae0463</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Goto, Ryosuke</creatorcontrib><creatorcontrib>Taminato, Sou</creatorcontrib><creatorcontrib>Mori, Daisuke</creatorcontrib><creatorcontrib>Imanishi, Nobuyuki</creatorcontrib><title>Synthesis and electrochemical properties of Li5+ x Fe1– x Mn x O4 with an antifluorite-type structure as a lithium battery cathode</title><title>Chemistry letters</title><description>A new antifluorite-structured Li5+xFe1–xMnxO4 was synthesized by conventional solid-state reaction and the lithium (de-)intercalation properties were characterized from electrochemical measurements. A single phase with a Li6MnO4-type structure was obtained for the x ≥ 0.6 compositions. The first discharge capacity of a Li5.6Fe0.4Mn0.6O4 (x = 0.6) electrode treated by ball milling was 450 mAh/g. The reversible reaction continued to proceed with ca. 200 mAh/g after subsequent cycles. A new iron–manganese system with an antifluorite structure could be a potential candidate as a high-capacity cathode material.</description><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqVj7FOwzAQhi0EEqGwMt-O0tpJmrYzomKgYoDdct2LYuTE0fkiyMbAG_CGPAmu6Asgnf77h_-_0yfErZJzJTflwrbYeVyMg0FZ1WciU2W1zuVKLc9FJsu6zleyKC7FVYxvUsr1piwy8fUy9dxidBFMfwD0aJnC8ZSzxsNAYUBihxFCA09ueQcfsEX18_mdzK5P8lzBu-M21dOwa_wYyDHmPA0IkWm0PBKCSQ_Ap6AbO9gbZqQJrOE2HPBaXDTGR7w57ZmYbx9e7x9zSyFGwkYP5DpDk1ZSH1n1H6s-sZb_LvwCFSpi4w</recordid><startdate>20240329</startdate><enddate>20240329</enddate><creator>Goto, Ryosuke</creator><creator>Taminato, Sou</creator><creator>Mori, Daisuke</creator><creator>Imanishi, Nobuyuki</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240329</creationdate><title>Synthesis and electrochemical properties of Li5+ x Fe1– x Mn x O4 with an antifluorite-type structure as a lithium battery cathode</title><author>Goto, Ryosuke ; Taminato, Sou ; Mori, Daisuke ; Imanishi, Nobuyuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-crossref_primary_10_1093_chemle_upae0463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Goto, Ryosuke</creatorcontrib><creatorcontrib>Taminato, Sou</creatorcontrib><creatorcontrib>Mori, Daisuke</creatorcontrib><creatorcontrib>Imanishi, Nobuyuki</creatorcontrib><collection>CrossRef</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Goto, Ryosuke</au><au>Taminato, Sou</au><au>Mori, Daisuke</au><au>Imanishi, Nobuyuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and electrochemical properties of Li5+ x Fe1– x Mn x O4 with an antifluorite-type structure as a lithium battery cathode</atitle><jtitle>Chemistry letters</jtitle><date>2024-03-29</date><risdate>2024</risdate><volume>53</volume><issue>4</issue><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>A new antifluorite-structured Li5+xFe1–xMnxO4 was synthesized by conventional solid-state reaction and the lithium (de-)intercalation properties were characterized from electrochemical measurements. A single phase with a Li6MnO4-type structure was obtained for the x ≥ 0.6 compositions. The first discharge capacity of a Li5.6Fe0.4Mn0.6O4 (x = 0.6) electrode treated by ball milling was 450 mAh/g. The reversible reaction continued to proceed with ca. 200 mAh/g after subsequent cycles. A new iron–manganese system with an antifluorite structure could be a potential candidate as a high-capacity cathode material.</abstract><doi>10.1093/chemle/upae046</doi></addata></record>
fulltext fulltext
identifier ISSN: 0366-7022
ispartof Chemistry letters, 2024-03, Vol.53 (4)
issn 0366-7022
1348-0715
language eng
recordid cdi_crossref_primary_10_1093_chemle_upae046
source Oxford University Press Journals All Titles (1996-Current)
title Synthesis and electrochemical properties of Li5+ x Fe1– x Mn x O4 with an antifluorite-type structure as a lithium battery cathode
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T14%3A54%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20electrochemical%20properties%20of%20Li5+%20x%20Fe1%E2%80%93%20x%20Mn%20x%20O4%20with%20an%20antifluorite-type%20structure%20as%20a%20lithium%20battery%20cathode&rft.jtitle=Chemistry%20letters&rft.au=Goto,%20Ryosuke&rft.date=2024-03-29&rft.volume=53&rft.issue=4&rft.issn=0366-7022&rft.eissn=1348-0715&rft_id=info:doi/10.1093/chemle/upae046&rft_dat=%3Ccrossref%3E10_1093_chemle_upae046%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true