Spherulites of supramolecular polymers formed from undercooled melts, and their adhesive properties

Spherulites of supramolecular polymers formed from undercooled melts, and their adhesive properties

The solid-state properties of crystalline supramolecular polymers have generally remained unexplored. Herein, we investigated the isothermal crystallization of a supramolecular polymer and showed that, depending on the temperature, it formed distinct structures at a higher hierarchical level. Intere...

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Veröffentlicht in:Chemistry letters 2024-02, Vol.53 (2)
Hauptverfasser: Shimada, Takuma, Watanabe, Yuichiro, Furuya, Tsutomu, Nishida, Koji, Samitsu, Sadaki, Wakayama, Yutaka, Sugiyasu, Kazunori
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container_issue 2
container_start_page
container_title Chemistry letters
container_volume 53
creator Shimada, Takuma
Watanabe, Yuichiro
Furuya, Tsutomu
Nishida, Koji
Samitsu, Sadaki
Wakayama, Yutaka
Sugiyasu, Kazunori
description The solid-state properties of crystalline supramolecular polymers have generally remained unexplored. Herein, we investigated the isothermal crystallization of a supramolecular polymer and showed that, depending on the temperature, it formed distinct structures at a higher hierarchical level. Interestingly, the resulting crystalline forms showed distinct adhesive properties and mechanical-failure modes (adhesive or cohesive).
doi_str_mv 10.1093/chemle/upad030
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source Oxford University Press Journals All Titles (1996-Current)
title Spherulites of supramolecular polymers formed from undercooled melts, and their adhesive properties
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