Properties of superconducting MgB 2 spherical shells deposited on 2 mm and 1 mm diameter Si 3 N 4 spheres

Superconducting spherical shells may not only provide an appealing platform for exploring superconductivity in three-dimensional (3D) geometries with curved surfaces, but also be practically applied in important fields, such as in gyroscopes and gravimeters. In inertial confinement fusion (ICF), the perturbation on the target capsule caused by traditional contact support methods is recognized as one of the major contributors to performance degradation in ICF implosions. It was proposed recently that coating the capsule with a thin superconducting MgB 2 spherical shell to realize non-contact support by means of magnetic levitation at the required temperatures ∼ 20 K might offer a promising solution to this longstanding problem. To simulate the coating of ICF capsules, we deposited MgB 2 spherical shells onto polycrystalline Si 3 N 4 spheres (diameter d = 2 mm and 1 mm) via a hybrid physical–chemical vapour deposition technique. For both diameters, the spherical shells, of about 1 µ m in thickness and covering the whole spheres completely, were polycrystalline with thin plate-shaped MgB 2 crystallites oriented randomly and closely connected. The spherical shells exhibited superconducting transition at a zero resistance temperature T c z e r o of 38.5–39.4 K in four-probe resistance measurements and ideal diamagnetism at low temperatures in magnetization measurements, suggesting the good crystallinity and homogeneity of the shells. The upper critical field H c 2 , the irreversibility field H i r r and the lower critical field H c 1 were characterized and showed similar magnitudes and temperature dependencies for the d = 2 mm and 1 mm shells, yielding H i r r of 7–8 T and H c 1 of 7–12 mT at 20 K. The superconducting critical current density J c values, evaluated from the magnetization hysteresis loops, were 1.8 × 10 6 A cm −2 and 8.5 × 10 4 A cm −2 at 20 K under zero and 2 T applied field, respectively, for the d = 1 mm shell. The occurrence of small flux jumps was observed at low temperatures up to 12 K and in low fields below 0.3 T. The results demonstrate the feasibility of fabricating MgB 2 spherical shells with properties applicable to potential areas employing magnetic levitation such as in ICF and that MgB 2 spherical shells may be exploited as an experimental system to study superconductivity in 3D curvilinear geometry.