Metal–insulator–metal micro-capacitors for integrated energy storage up to 10 5 Hz

Metal–insulator–metal (MIM) micro-capacitors for use in integrated energy storage applications are presented. A new, simple and batch Si processing compatible method for the creation of high aspect ratio metallic 3D structures on the surface of a Si substrate is described. The method consists of creating an array of Si nanopillars and then depositing Al at a small angle off the vertical while rotating the sample. Using this method, the effective area of the samples is increased by a factor of 3.8. Various capacitors are created using the described 3D structures as the lower electrode, with anodic alumina and atomic layer deposited HfO 2 as the dielectric. Al and Cu top electrodes are also investigated. Large values of capacitance densities as high as 3.2 μ F cm −2 are achieved. All capacitors are demonstrated to possess small values of series resistances and stable operation up to a frequency of 10 5 Hz. These results make the presented MIM capacitors exceed the state-of-the-art while maintaining a simple and integrable fabrication scheme which renders them very interesting for energy storage applications where operational frequencies larger than 1 kHz are required, as is the case in several vibrational energy harvesters.