Adsorption of Metallic Cations on Silica Gel-Immobilized 8-Hydroxyquinoline

TLC-grade silica gel was functionalized with 8-hydroxyquinoline via a catalyzed Mannich amminomethylation reaction. The resulting solid was characterized by FT-IR and used as a sorbent for 0.05-5 mmol·L −1 Cu(II), Cd(II), Zn(II), Pb(II), and Fe(III) from aqueous solutions in the batch mode. Experime...

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Veröffentlicht in:Separation science and technology 2000-01, Vol.35 (10), p.1661-1679
Hauptverfasser: BERNAL, J. P., DE SAN MIGUEL, E. RODRÍGUEZ, AGUILAR, J. C., SALAZAR, G., DE GYVES, J.
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container_end_page 1679
container_issue 10
container_start_page 1661
container_title Separation science and technology
container_volume 35
creator BERNAL, J. P.
DE SAN MIGUEL, E. RODRÍGUEZ
AGUILAR, J. C.
SALAZAR, G.
DE GYVES, J.
description TLC-grade silica gel was functionalized with 8-hydroxyquinoline via a catalyzed Mannich amminomethylation reaction. The resulting solid was characterized by FT-IR and used as a sorbent for 0.05-5 mmol·L −1 Cu(II), Cd(II), Zn(II), Pb(II), and Fe(III) from aqueous solutions in the batch mode. Experiments were carried out in both single and multiple cation solutions. The influence of the aqueous media composition on the adsorption process, the possible adsorbed species, and the adsorption kinetics are discussed. Overall equilibrium constants for these processes are reported.
doi_str_mv 10.1081/SS-100100247
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title Adsorption of Metallic Cations on Silica Gel-Immobilized 8-Hydroxyquinoline
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